A Molecular Nanotube with Three-Dimensional π-Conjugation**

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A π-conjugated twelve-porphyrin tube is synthesized in 32 % yield by a template-directed coupling reaction that joins together six porphyrin dimers, forming twelve new C=C bonds. The nanotube has two bound templates, enclosing an internal volume of approximately 4.5 nm(3). Its UV/Vis/NIR absorption...

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Detalles Bibliográficos
Autores principales: Neuhaus, Patrik, Cnossen, Arjen, Gong, Juliane Q, Herz, Laura M, Anderson, Harry L
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4510782/
https://www.ncbi.nlm.nih.gov/pubmed/25950655
http://dx.doi.org/10.1002/anie.201502735
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