Rate and Equilibrium Constants for the Addition of N-Heterocyclic Carbenes into Benzaldehydes: A Remarkable 2-Substituent Effect**

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Rate and equilibrium constants for the reaction between N-aryl triazolium N-heterocyclic carbene (NHC) precatalysts and substituted benzaldehyde derivatives to form 3-(hydroxybenzyl)azolium adducts under both catalytic and stoichiometric conditions have been measured. Kinetic analysis and reaction p...

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Detalles Bibliográficos
Autores principales: Collett, Christopher J, Massey, Richard S, Taylor, James E, Maguire, Oliver R, O'Donoghue, AnnMarie C, Smith, Andrew D
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4510784/
https://www.ncbi.nlm.nih.gov/pubmed/25908493
http://dx.doi.org/10.1002/anie.201501840

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4510784/
https://www.ncbi.nlm.nih.gov/pubmed/25908493
http://dx.doi.org/10.1002/anie.201501840

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