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Rate and Equilibrium Constants for the Addition of N-Heterocyclic Carbenes into Benzaldehydes: A Remarkable 2-Substituent Effect**
Rate and equilibrium constants for the reaction between N-aryl triazolium N-heterocyclic carbene (NHC) precatalysts and substituted benzaldehyde derivatives to form 3-(hydroxybenzyl)azolium adducts under both catalytic and stoichiometric conditions have been measured. Kinetic analysis and reaction p...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
WILEY-VCH Verlag
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4510784/ https://www.ncbi.nlm.nih.gov/pubmed/25908493 http://dx.doi.org/10.1002/anie.201501840 |
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por Collett, Christopher J., Massey, Richard S., Taylor, James E., Maguire, Oliver R., O'Donoghue, AnnMarie C., Smith, Andrew D.
Publicado 2015
Enlace del recurso
Publicado 2015
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Enlace del recurso
Online
Artículo
Texto