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Graphene mobility mapping

Carrier mobility and chemical doping level are essential figures of merit for graphene, and large-scale characterization of these properties and their uniformity is a prerequisite for commercialization of graphene for electronics and electrodes. However, existing mapping techniques cannot directly a...

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Autores principales: Buron, Jonas D., Pizzocchero, Filippo, Jepsen, Peter U., Petersen, Dirch H., Caridad, José M., Jessen, Bjarke S., Booth, Timothy J., Bøggild, Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4513276/
https://www.ncbi.nlm.nih.gov/pubmed/26204815
http://dx.doi.org/10.1038/srep12305
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author Buron, Jonas D.
Pizzocchero, Filippo
Jepsen, Peter U.
Petersen, Dirch H.
Caridad, José M.
Jessen, Bjarke S.
Booth, Timothy J.
Bøggild, Peter
author_facet Buron, Jonas D.
Pizzocchero, Filippo
Jepsen, Peter U.
Petersen, Dirch H.
Caridad, José M.
Jessen, Bjarke S.
Booth, Timothy J.
Bøggild, Peter
author_sort Buron, Jonas D.
collection PubMed
description Carrier mobility and chemical doping level are essential figures of merit for graphene, and large-scale characterization of these properties and their uniformity is a prerequisite for commercialization of graphene for electronics and electrodes. However, existing mapping techniques cannot directly assess these vital parameters in a non-destructive way. By deconvoluting carrier mobility and density from non-contact terahertz spectroscopic measurements of conductance in graphene samples with terahertz-transparent backgates, we are able to present maps of the spatial variation of both quantities over large areas. The demonstrated non-contact approach provides a drastically more efficient alternative to measurements in contacted devices, with potential for aggressive scaling towards wafers/minute. The observed linear relation between conductance and carrier density in chemical vapour deposition graphene indicates dominance by charged scatterers. Unexpectedly, significant variations in mobility rather than doping are the cause of large conductance inhomogeneities, highlighting the importance of statistical approaches when assessing large-area graphene transport properties.
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spelling pubmed-45132762015-07-29 Graphene mobility mapping Buron, Jonas D. Pizzocchero, Filippo Jepsen, Peter U. Petersen, Dirch H. Caridad, José M. Jessen, Bjarke S. Booth, Timothy J. Bøggild, Peter Sci Rep Article Carrier mobility and chemical doping level are essential figures of merit for graphene, and large-scale characterization of these properties and their uniformity is a prerequisite for commercialization of graphene for electronics and electrodes. However, existing mapping techniques cannot directly assess these vital parameters in a non-destructive way. By deconvoluting carrier mobility and density from non-contact terahertz spectroscopic measurements of conductance in graphene samples with terahertz-transparent backgates, we are able to present maps of the spatial variation of both quantities over large areas. The demonstrated non-contact approach provides a drastically more efficient alternative to measurements in contacted devices, with potential for aggressive scaling towards wafers/minute. The observed linear relation between conductance and carrier density in chemical vapour deposition graphene indicates dominance by charged scatterers. Unexpectedly, significant variations in mobility rather than doping are the cause of large conductance inhomogeneities, highlighting the importance of statistical approaches when assessing large-area graphene transport properties. Nature Publishing Group 2015-07-24 /pmc/articles/PMC4513276/ /pubmed/26204815 http://dx.doi.org/10.1038/srep12305 Text en Copyright © 2015, Macmillan Publishers Limited http://creativecommons.org/licenses/by/4.0/ This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/
spellingShingle Article
Buron, Jonas D.
Pizzocchero, Filippo
Jepsen, Peter U.
Petersen, Dirch H.
Caridad, José M.
Jessen, Bjarke S.
Booth, Timothy J.
Bøggild, Peter
Graphene mobility mapping
title Graphene mobility mapping
title_full Graphene mobility mapping
title_fullStr Graphene mobility mapping
title_full_unstemmed Graphene mobility mapping
title_short Graphene mobility mapping
title_sort graphene mobility mapping
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4513276/
https://www.ncbi.nlm.nih.gov/pubmed/26204815
http://dx.doi.org/10.1038/srep12305
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