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Determination of (210)Po and uranium in high salinity water samples
A method for the determination of uranium and (210)Po in high salinity water samples has been elaborated. Both radionuclides are preconcentrated from 0.5 dm(3) saline media by co-precipitation with hydrated manganese dioxide, followed by dissolution of the precipitate in 200 mL of 1 M HCl. Uranium i...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Springer Netherlands
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4514583/ https://www.ncbi.nlm.nih.gov/pubmed/26224904 http://dx.doi.org/10.1007/s10967-010-0720-4 |
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author | Grabowski, Paweł Bem, Henryk |
author_facet | Grabowski, Paweł Bem, Henryk |
author_sort | Grabowski, Paweł |
collection | PubMed |
description | A method for the determination of uranium and (210)Po in high salinity water samples has been elaborated. Both radionuclides are preconcentrated from 0.5 dm(3) saline media by co-precipitation with hydrated manganese dioxide, followed by dissolution of the precipitate in 200 mL of 1 M HCl. Uranium isotopes (235)U and (238)U can be directly determined by ICP MS method with a detection limit of 0.01 ppb for (238)U. Prior to a selective determination of (210)Po, the majority of other naturally occurring α-emitting radionuclides (uranium, thorium and protactinium) can be stripped from this solution by their extraction with a 50% solution of HDEHP in toluene. Finally, (210)Po is simply separated by direct transfer to an extractive scintillator containing 5% of trioctylphosphine oxide in Ultima Gold F cocktail and determined by an α/β separation liquid scintillation technique with detection limit below 0.1 mBq/dm(3). |
format | Online Article Text |
id | pubmed-4514583 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | Springer Netherlands |
record_format | MEDLINE/PubMed |
spelling | pubmed-45145832015-07-27 Determination of (210)Po and uranium in high salinity water samples Grabowski, Paweł Bem, Henryk J Radioanal Nucl Chem Article A method for the determination of uranium and (210)Po in high salinity water samples has been elaborated. Both radionuclides are preconcentrated from 0.5 dm(3) saline media by co-precipitation with hydrated manganese dioxide, followed by dissolution of the precipitate in 200 mL of 1 M HCl. Uranium isotopes (235)U and (238)U can be directly determined by ICP MS method with a detection limit of 0.01 ppb for (238)U. Prior to a selective determination of (210)Po, the majority of other naturally occurring α-emitting radionuclides (uranium, thorium and protactinium) can be stripped from this solution by their extraction with a 50% solution of HDEHP in toluene. Finally, (210)Po is simply separated by direct transfer to an extractive scintillator containing 5% of trioctylphosphine oxide in Ultima Gold F cocktail and determined by an α/β separation liquid scintillation technique with detection limit below 0.1 mBq/dm(3). Springer Netherlands 2010-08-19 2010 /pmc/articles/PMC4514583/ /pubmed/26224904 http://dx.doi.org/10.1007/s10967-010-0720-4 Text en © The Author(s) 2010 https://creativecommons.org/licenses/by-nc/4.0/ This article is distributed under the terms of the Creative Commons Attribution Noncommercial License which permits any noncommercial use, distribution, and reproduction in any medium, provided the original author(s) and source are credited. |
spellingShingle | Article Grabowski, Paweł Bem, Henryk Determination of (210)Po and uranium in high salinity water samples |
title | Determination of (210)Po and uranium in high salinity water samples |
title_full | Determination of (210)Po and uranium in high salinity water samples |
title_fullStr | Determination of (210)Po and uranium in high salinity water samples |
title_full_unstemmed | Determination of (210)Po and uranium in high salinity water samples |
title_short | Determination of (210)Po and uranium in high salinity water samples |
title_sort | determination of (210)po and uranium in high salinity water samples |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4514583/ https://www.ncbi.nlm.nih.gov/pubmed/26224904 http://dx.doi.org/10.1007/s10967-010-0720-4 |
work_keys_str_mv | AT grabowskipaweł determinationof210poanduraniuminhighsalinitywatersamples AT bemhenryk determinationof210poanduraniuminhighsalinitywatersamples |