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A Versatile Room-Temperature Route to Di- and Trisubstituted Allenes Using Flow-Generated Diazo Compounds**
A copper-catalyzed coupling reaction between flow-generated unstabilized diazo compounds and terminal alkynes provides di- and trisubstituted allenes. This extremely mild and rapid transformation is highly tolerant of several functional groups.
Autores principales: | Poh, Jian-Siang, Tran, Duc N, Battilocchio, Claudio, Hawkins, Joel M, Ley, Steven V |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
WILEY-VCH Verlag
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4515080/ https://www.ncbi.nlm.nih.gov/pubmed/26013774 http://dx.doi.org/10.1002/anie.201501538 |
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