Non-linear, cata-Condensed, Polycyclic Aromatic Hydrocarbon Materials: A Generic Approach and Physical Properties

A generic approach to the regiospecific synthesis of halogenated polycyclic aromatics is made possible by the one- or two-directional benzannulation reactions of readily available (ortho-allylaryl)trichloroacetates (the “BHQ” reaction). Palladium-catalysed cross-coupling reactions of the so-formed h...

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Detalles Bibliográficos
Autores principales: Haire, Barnaby T, Heard, Kane W J, Little, Mark S, Parry, Adam V S, Raftery, James, Quayle, Peter, Yeates, Stephen G
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4515081/
https://www.ncbi.nlm.nih.gov/pubmed/26059760
http://dx.doi.org/10.1002/chem.201501861
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author Haire, Barnaby T
Heard, Kane W J
Little, Mark S
Parry, Adam V S
Raftery, James
Quayle, Peter
Yeates, Stephen G
author_facet Haire, Barnaby T
Heard, Kane W J
Little, Mark S
Parry, Adam V S
Raftery, James
Quayle, Peter
Yeates, Stephen G
author_sort Haire, Barnaby T
collection PubMed
description A generic approach to the regiospecific synthesis of halogenated polycyclic aromatics is made possible by the one- or two-directional benzannulation reactions of readily available (ortho-allylaryl)trichloroacetates (the “BHQ” reaction). Palladium-catalysed cross-coupling reactions of the so-formed haloaromatics enable the synthesis of functionalised polycyclic aromatic hydrocarbons (PAHs) with surgical precision. Overall, this new methodology enables the facile mining of chemical space in search of new electronic functional materials.
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spelling pubmed-45150812015-07-31 Non-linear, cata-Condensed, Polycyclic Aromatic Hydrocarbon Materials: A Generic Approach and Physical Properties Haire, Barnaby T Heard, Kane W J Little, Mark S Parry, Adam V S Raftery, James Quayle, Peter Yeates, Stephen G Chemistry Communications A generic approach to the regiospecific synthesis of halogenated polycyclic aromatics is made possible by the one- or two-directional benzannulation reactions of readily available (ortho-allylaryl)trichloroacetates (the “BHQ” reaction). Palladium-catalysed cross-coupling reactions of the so-formed haloaromatics enable the synthesis of functionalised polycyclic aromatic hydrocarbons (PAHs) with surgical precision. Overall, this new methodology enables the facile mining of chemical space in search of new electronic functional materials. WILEY-VCH Verlag 2015-07-06 2015-06-08 /pmc/articles/PMC4515081/ /pubmed/26059760 http://dx.doi.org/10.1002/chem.201501861 Text en © 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim http://creativecommons.org/licenses/by/3.0/ This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Haire, Barnaby T
Heard, Kane W J
Little, Mark S
Parry, Adam V S
Raftery, James
Quayle, Peter
Yeates, Stephen G
Non-linear, cata-Condensed, Polycyclic Aromatic Hydrocarbon Materials: A Generic Approach and Physical Properties
title Non-linear, cata-Condensed, Polycyclic Aromatic Hydrocarbon Materials: A Generic Approach and Physical Properties
title_full Non-linear, cata-Condensed, Polycyclic Aromatic Hydrocarbon Materials: A Generic Approach and Physical Properties
title_fullStr Non-linear, cata-Condensed, Polycyclic Aromatic Hydrocarbon Materials: A Generic Approach and Physical Properties
title_full_unstemmed Non-linear, cata-Condensed, Polycyclic Aromatic Hydrocarbon Materials: A Generic Approach and Physical Properties
title_short Non-linear, cata-Condensed, Polycyclic Aromatic Hydrocarbon Materials: A Generic Approach and Physical Properties
title_sort non-linear, cata-condensed, polycyclic aromatic hydrocarbon materials: a generic approach and physical properties
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4515081/
https://www.ncbi.nlm.nih.gov/pubmed/26059760
http://dx.doi.org/10.1002/chem.201501861
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