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Exploiting the Brønsted Acidity of Phosphinecarboxamides for the Synthesis of New Phosphides and Phosphines
We demonstrate that the synthesis of new N-functionalized phosphinecarboxamides is possible by reaction of primary and secondary amines with PCO(−) in the presence of a proton source. These reactions proceed with varying degrees of success, and although primary amines generally afford the correspond...
Autores principales: | Jupp, Andrew R, Trott, Gemma, Payen de la Garanderie, Éléonore, Holl, James D G, Carmichael, Duncan, Goicoechea, Jose M |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
WILEY-VCH Verlag
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4515089/ https://www.ncbi.nlm.nih.gov/pubmed/25892576 http://dx.doi.org/10.1002/chem.201501174 |
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