Enantioselective Synthesis and Application to the Allylic Imidate Rearrangement of Amine-Coordinated Palladacycle Catalysts of Cobalt Sandwich Complexes

The reaction of (η(5)-(N,N-dimethylaminomethyl)cyclopentadien-yl)(η(4)-tetraphenylcyclobutadiene)cobalt with sodium tetrachloropalladate and (R)-N-acetylphenylalanine gave planar chiral palladacycle di-μ-chloridebis[(η(5)-(S(p))-2-(N,N-dimethylaminomethyl)cyclopentadienyl,1-C,3′-N)(η(4)-tetraphenylc...

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Detalles Bibliográficos
Autores principales: Cassar, Doyle J, Ilyashenko, Gennadiy, Ismail, Muhammad, Woods, James, Hughes, David L, Richards, Christopher J
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2013
Materias:
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Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4517145/
https://www.ncbi.nlm.nih.gov/pubmed/24264943
http://dx.doi.org/10.1002/chem.201302922

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