An Inverted-Sandwich Diuranium μ-η(5):η(5)-Cyclo-P(5) Complex Supported by U-P(5) δ-Bonding**

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Reaction of [U(Tren(TIPS))] [1, Tren(TIPS)=N(CH(2)CH(2)NSiiPr(3))(3)] with 0.25 equivalents of P(4) reproducibly affords the unprecedented actinide inverted sandwich cyclo-P(5) complex [{U(Tren(TIPS))}(2)(μ-η(5):η(5)-cyclo-P(5))] (2). All prior examples of cyclo-P(5) are stabilized by d-block metals...

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Detalles Bibliográficos
Autores principales: Gardner, Benedict M, Tuna, Floriana, McInnes, Eric J L, McMaster, Jonathan, Lewis, William, Blake, Alexander J, Liddle, Stephen T
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4517156/
https://www.ncbi.nlm.nih.gov/pubmed/25914060
http://dx.doi.org/10.1002/anie.201501728
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