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Crystal structure of N-[(morpholin-4-yl)(thio­phen-2-yl)meth­yl]benzamide

In the title compound, C(16)H(18)N(2)O(2)S, the morpholine ring adopts a chair conformation. The thio­phene ring makes a dihedral angle of 63.54 (14)° with the mean plane of the four C atoms [maximum deviation = 0.010 (3) Å] of the morpholine ring. The benzamide ring is disordered, with four C atoms...

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Detalles Bibliográficos
Autores principales: Prabhu, S. Arun, Suresh, M., Jameel, A. Abdul, Padusha, M. Syed Ali, Gunasekaran, B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518906/
https://www.ncbi.nlm.nih.gov/pubmed/26279929
http://dx.doi.org/10.1107/S2056989015011639
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author Prabhu, S. Arun
Suresh, M.
Jameel, A. Abdul
Padusha, M. Syed Ali
Gunasekaran, B.
author_facet Prabhu, S. Arun
Suresh, M.
Jameel, A. Abdul
Padusha, M. Syed Ali
Gunasekaran, B.
author_sort Prabhu, S. Arun
collection PubMed
description In the title compound, C(16)H(18)N(2)O(2)S, the morpholine ring adopts a chair conformation. The thio­phene ring makes a dihedral angle of 63.54 (14)° with the mean plane of the four C atoms [maximum deviation = 0.010 (3) Å] of the morpholine ring. The benzamide ring is disordered, with four C atoms occupying two sets of sites, with a refined occupancy ratio of 0.502 (4):0.498 (4). These two rings are inclined to one another by 85.2 (4)° and to the thio­phene ring by 72.7 (3) and 13.0 (3)° for the major and minor components, respectively. In the crystal, mol­ecules are linked via N—H⋯O hydrogen bonds, forming chains along [001].
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spelling pubmed-45189062015-08-14 Crystal structure of N-[(morpholin-4-yl)(thio­phen-2-yl)meth­yl]benzamide Prabhu, S. Arun Suresh, M. Jameel, A. Abdul Padusha, M. Syed Ali Gunasekaran, B. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(16)H(18)N(2)O(2)S, the morpholine ring adopts a chair conformation. The thio­phene ring makes a dihedral angle of 63.54 (14)° with the mean plane of the four C atoms [maximum deviation = 0.010 (3) Å] of the morpholine ring. The benzamide ring is disordered, with four C atoms occupying two sets of sites, with a refined occupancy ratio of 0.502 (4):0.498 (4). These two rings are inclined to one another by 85.2 (4)° and to the thio­phene ring by 72.7 (3) and 13.0 (3)° for the major and minor components, respectively. In the crystal, mol­ecules are linked via N—H⋯O hydrogen bonds, forming chains along [001]. International Union of Crystallography 2015-06-20 /pmc/articles/PMC4518906/ /pubmed/26279929 http://dx.doi.org/10.1107/S2056989015011639 Text en © Prabhu et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Prabhu, S. Arun
Suresh, M.
Jameel, A. Abdul
Padusha, M. Syed Ali
Gunasekaran, B.
Crystal structure of N-[(morpholin-4-yl)(thio­phen-2-yl)meth­yl]benzamide
title Crystal structure of N-[(morpholin-4-yl)(thio­phen-2-yl)meth­yl]benzamide
title_full Crystal structure of N-[(morpholin-4-yl)(thio­phen-2-yl)meth­yl]benzamide
title_fullStr Crystal structure of N-[(morpholin-4-yl)(thio­phen-2-yl)meth­yl]benzamide
title_full_unstemmed Crystal structure of N-[(morpholin-4-yl)(thio­phen-2-yl)meth­yl]benzamide
title_short Crystal structure of N-[(morpholin-4-yl)(thio­phen-2-yl)meth­yl]benzamide
title_sort crystal structure of n-[(morpholin-4-yl)(thio­phen-2-yl)meth­yl]benzamide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518906/
https://www.ncbi.nlm.nih.gov/pubmed/26279929
http://dx.doi.org/10.1107/S2056989015011639
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