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Crystal structure of (E)-dodec-2-enoic acid
The crystal structure of (E)-dodec-2-enoic acid, C(12)H(22)O(2), an α,β-unsaturated carboxylic acid with a melting point (295 K) near room temperature, is characterized by carboxylic acid inversion dimers linked by pairs of O—H⋯O hydrogen bonds. The carboxylic acid group and the following thre...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518913/ https://www.ncbi.nlm.nih.gov/pubmed/26279945 http://dx.doi.org/10.1107/S2056989015011937 |
Sumario: | The crystal structure of (E)-dodec-2-enoic acid, C(12)H(22)O(2), an α,β-unsaturated carboxylic acid with a melting point (295 K) near room temperature, is characterized by carboxylic acid inversion dimers linked by pairs of O—H⋯O hydrogen bonds. The carboxylic acid group and the following three carbon atoms of the chain of the (E)-dodec-2-enoic acid molecule lie almost in one plane (r.m.s. deviation for the four C atoms and two O atoms = 0.012 Å), whereas the remaining carbon atoms of the hydrocarbon chain adopt a nearly fully staggered conformation [moduli of torsion angles vary from 174.01 (13) to 179.97 (13)°]. |
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