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Crystal structure of 3-(hy­droxy­meth­yl)chromone

In the title compound, C(10)H(8)O(3) (systematic name 3-hy­droxy­methyl-4H-chromen-4-one), the fused-ring system is slightly puckered [dihedral angle between the rings = 3.84 (11)°]. The hy­droxy O atom deviates from the heterocyclic ring by 1.422 (1) Å. In the crystal, inversion dimers linked by pa...

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Detalles Bibliográficos
Autor principal: Ishikawa, Yoshinobu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518918/
https://www.ncbi.nlm.nih.gov/pubmed/26279927
http://dx.doi.org/10.1107/S2056989015011627
Descripción
Sumario:In the title compound, C(10)H(8)O(3) (systematic name 3-hy­droxy­methyl-4H-chromen-4-one), the fused-ring system is slightly puckered [dihedral angle between the rings = 3.84 (11)°]. The hy­droxy O atom deviates from the heterocyclic ring by 1.422 (1) Å. In the crystal, inversion dimers linked by pairs of O—H⋯O hydrogen bonds generate R (2) (2)(12) loops. The dimers are linked by aromatic π–π stacking [shortest centroid–centroid distance = 3.580 (3) Å], and C—H⋯O hydrogen bonds, generating a three-dimensional network.