Crystal structure of a second polymorph of 2-cyclo­penta­dienyl-1,7-dicarba-2-cobalta-closo-dodeca­borane(11)

A new polymorph of the title compound 2-(η-C(5)H(5))-2,1,7-closo-CoC(2)B(9)H(11), [Co(C(5)H(5))(C(2)H(11)B(9))], in the space group P2(1)/n has been characterized, including the unambiguous location of both cage C atoms. The precision of this study is an order of magnitude greater than that of the f...

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Detalles Bibliográficos
Autores principales: Man, Wing Y., Rosair, Georgina M., Welch, Alan J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518921/
https://www.ncbi.nlm.nih.gov/pubmed/26279892
http://dx.doi.org/10.1107/S2056989015011445
Descripción
Sumario:A new polymorph of the title compound 2-(η-C(5)H(5))-2,1,7-closo-CoC(2)B(9)H(11), [Co(C(5)H(5))(C(2)H(11)B(9))], in the space group P2(1)/n has been characterized, including the unambiguous location of both cage C atoms. The precision of this study is an order of magnitude greater than that of the first polymorph [C2/c; Lopez et al. (2010). Collect. Czech. Chem. Commun. 75, 853–869].

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