Crystal structure of a second polymorph of 2-cyclo­penta­dienyl-1,7-dicarba-2-cobalta-closo-dodeca­borane(11)

A new polymorph of the title compound 2-(η-C(5)H(5))-2,1,7-closo-CoC(2)B(9)H(11), [Co(C(5)H(5))(C(2)H(11)B(9))], in the space group P2(1)/n has been characterized, including the unambiguous location of both cage C atoms. The precision of this study is an order of magnitude greater than that of the f...

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Detalles Bibliográficos
Autores principales: Man, Wing Y., Rosair, Georgina M., Welch, Alan J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518921/
https://www.ncbi.nlm.nih.gov/pubmed/26279892
http://dx.doi.org/10.1107/S2056989015011445
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author Man, Wing Y.
Rosair, Georgina M.
Welch, Alan J.
author_facet Man, Wing Y.
Rosair, Georgina M.
Welch, Alan J.
author_sort Man, Wing Y.
collection PubMed
description A new polymorph of the title compound 2-(η-C(5)H(5))-2,1,7-closo-CoC(2)B(9)H(11), [Co(C(5)H(5))(C(2)H(11)B(9))], in the space group P2(1)/n has been characterized, including the unambiguous location of both cage C atoms. The precision of this study is an order of magnitude greater than that of the first polymorph [C2/c; Lopez et al. (2010). Collect. Czech. Chem. Commun. 75, 853–869].
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spelling pubmed-45189212015-08-14 Crystal structure of a second polymorph of 2-cyclo­penta­dienyl-1,7-dicarba-2-cobalta-closo-dodeca­borane(11) Man, Wing Y. Rosair, Georgina M. Welch, Alan J. Acta Crystallogr E Crystallogr Commun Data Reports A new polymorph of the title compound 2-(η-C(5)H(5))-2,1,7-closo-CoC(2)B(9)H(11), [Co(C(5)H(5))(C(2)H(11)B(9))], in the space group P2(1)/n has been characterized, including the unambiguous location of both cage C atoms. The precision of this study is an order of magnitude greater than that of the first polymorph [C2/c; Lopez et al. (2010). Collect. Czech. Chem. Commun. 75, 853–869]. International Union of Crystallography 2015-06-17 /pmc/articles/PMC4518921/ /pubmed/26279892 http://dx.doi.org/10.1107/S2056989015011445 Text en © Man et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Man, Wing Y.
Rosair, Georgina M.
Welch, Alan J.
Crystal structure of a second polymorph of 2-cyclo­penta­dienyl-1,7-dicarba-2-cobalta-closo-dodeca­borane(11)
title Crystal structure of a second polymorph of 2-cyclo­penta­dienyl-1,7-dicarba-2-cobalta-closo-dodeca­borane(11)
title_full Crystal structure of a second polymorph of 2-cyclo­penta­dienyl-1,7-dicarba-2-cobalta-closo-dodeca­borane(11)
title_fullStr Crystal structure of a second polymorph of 2-cyclo­penta­dienyl-1,7-dicarba-2-cobalta-closo-dodeca­borane(11)
title_full_unstemmed Crystal structure of a second polymorph of 2-cyclo­penta­dienyl-1,7-dicarba-2-cobalta-closo-dodeca­borane(11)
title_short Crystal structure of a second polymorph of 2-cyclo­penta­dienyl-1,7-dicarba-2-cobalta-closo-dodeca­borane(11)
title_sort crystal structure of a second polymorph of 2-cyclo­penta­dienyl-1,7-dicarba-2-cobalta-closo-dodeca­borane(11)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518921/
https://www.ncbi.nlm.nih.gov/pubmed/26279892
http://dx.doi.org/10.1107/S2056989015011445
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