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Crystal structure of 4-methyl­benzyl N′-[(thio­phen-2-yl)methyl­idene]hydrazinecarbodi­thio­ate

In the title compound, C(15)H(16)N(2)S(3) {systematic name: [({[(4-methyl­phen­yl)meth­yl]sulfan­yl}methane­thio­yl)amino][1-(thio­phen-2-yl)ethyl­idene]amine}, the central CN(2)S(2) residue is almost planar (r.m.s. deviation = 0.0061 Å) and forms dihedral angles of 7.39 (10) and 64.91 (5)° with the...

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Autores principales: Ramli, Syahirah binti, Ravoof, Thahira Begum S. A., Tahir, Mohamed Ibrahim Mohamed, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518925/
https://www.ncbi.nlm.nih.gov/pubmed/26279916
http://dx.doi.org/10.1107/S205698901501107X
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author Ramli, Syahirah binti
Ravoof, Thahira Begum S. A.
Tahir, Mohamed Ibrahim Mohamed
Tiekink, Edward R. T.
author_facet Ramli, Syahirah binti
Ravoof, Thahira Begum S. A.
Tahir, Mohamed Ibrahim Mohamed
Tiekink, Edward R. T.
author_sort Ramli, Syahirah binti
collection PubMed
description In the title compound, C(15)H(16)N(2)S(3) {systematic name: [({[(4-methyl­phen­yl)meth­yl]sulfan­yl}methane­thio­yl)amino][1-(thio­phen-2-yl)ethyl­idene]amine}, the central CN(2)S(2) residue is almost planar (r.m.s. deviation = 0.0061 Å) and forms dihedral angles of 7.39 (10) and 64.91 (5)° with the thienyl and p-tolyl rings, respectively; the dihedral angle between these rings is 57.52 (6)°. The non-thione S atoms are syn, and with respect to the thione S atom, the benzyl group is anti. In the crystal, centrosymmetrically related mol­ecules self-associate via eight-membered {⋯HNCS}(2) synthons. The dimeric aggregates stack along the a axis and are are consolidated into a three-dimensional architecture via methyl-C—H⋯π(benzene) and benzene-C—H⋯π(thien­yl) inter­actions.
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spelling pubmed-45189252015-08-14 Crystal structure of 4-methyl­benzyl N′-[(thio­phen-2-yl)methyl­idene]hydrazinecarbodi­thio­ate Ramli, Syahirah binti Ravoof, Thahira Begum S. A. Tahir, Mohamed Ibrahim Mohamed Tiekink, Edward R. T. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(15)H(16)N(2)S(3) {systematic name: [({[(4-methyl­phen­yl)meth­yl]sulfan­yl}methane­thio­yl)amino][1-(thio­phen-2-yl)ethyl­idene]amine}, the central CN(2)S(2) residue is almost planar (r.m.s. deviation = 0.0061 Å) and forms dihedral angles of 7.39 (10) and 64.91 (5)° with the thienyl and p-tolyl rings, respectively; the dihedral angle between these rings is 57.52 (6)°. The non-thione S atoms are syn, and with respect to the thione S atom, the benzyl group is anti. In the crystal, centrosymmetrically related mol­ecules self-associate via eight-membered {⋯HNCS}(2) synthons. The dimeric aggregates stack along the a axis and are are consolidated into a three-dimensional architecture via methyl-C—H⋯π(benzene) and benzene-C—H⋯π(thien­yl) inter­actions. International Union of Crystallography 2015-06-13 /pmc/articles/PMC4518925/ /pubmed/26279916 http://dx.doi.org/10.1107/S205698901501107X Text en © Ramli et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Ramli, Syahirah binti
Ravoof, Thahira Begum S. A.
Tahir, Mohamed Ibrahim Mohamed
Tiekink, Edward R. T.
Crystal structure of 4-methyl­benzyl N′-[(thio­phen-2-yl)methyl­idene]hydrazinecarbodi­thio­ate
title Crystal structure of 4-methyl­benzyl N′-[(thio­phen-2-yl)methyl­idene]hydrazinecarbodi­thio­ate
title_full Crystal structure of 4-methyl­benzyl N′-[(thio­phen-2-yl)methyl­idene]hydrazinecarbodi­thio­ate
title_fullStr Crystal structure of 4-methyl­benzyl N′-[(thio­phen-2-yl)methyl­idene]hydrazinecarbodi­thio­ate
title_full_unstemmed Crystal structure of 4-methyl­benzyl N′-[(thio­phen-2-yl)methyl­idene]hydrazinecarbodi­thio­ate
title_short Crystal structure of 4-methyl­benzyl N′-[(thio­phen-2-yl)methyl­idene]hydrazinecarbodi­thio­ate
title_sort crystal structure of 4-methyl­benzyl n′-[(thio­phen-2-yl)methyl­idene]hydrazinecarbodi­thio­ate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518925/
https://www.ncbi.nlm.nih.gov/pubmed/26279916
http://dx.doi.org/10.1107/S205698901501107X
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