Cargando…

Crystal structure of (2-hy­droxy-5-methyl­phen­yl)(3-methyl-1-phenyl-1H-pyrazolo­[3,4-b]pyridin-5-yl)methanone

In the title compound, C(21)H(17)N(3)O(2), the 2-hy­droxy-5-methyl­phenyl ring and the phenyl ring are inclined to the mean plane of the pyrazolo­pyridine moiety (r.m.s. deviation = 0.013 Å) by 52.89 (9) and 19.63 (8)°, respectively, and to each other by 42.83 (11)°. In the mol­ecule, there are intr...

Descripción completa

Detalles Bibliográficos
Autores principales: Raja, Rajamani, Poomathi, Nataraj, Perumal, Paramasivam T., SubbiahPandi, A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518926/
https://www.ncbi.nlm.nih.gov/pubmed/26279931
http://dx.doi.org/10.1107/S2056989015011597
_version_ 1782383426734653440
author Raja, Rajamani
Poomathi, Nataraj
Perumal, Paramasivam T.
SubbiahPandi, A.
author_facet Raja, Rajamani
Poomathi, Nataraj
Perumal, Paramasivam T.
SubbiahPandi, A.
author_sort Raja, Rajamani
collection PubMed
description In the title compound, C(21)H(17)N(3)O(2), the 2-hy­droxy-5-methyl­phenyl ring and the phenyl ring are inclined to the mean plane of the pyrazolo­pyridine moiety (r.m.s. deviation = 0.013 Å) by 52.89 (9) and 19.63 (8)°, respectively, and to each other by 42.83 (11)°. In the mol­ecule, there are intra­molecular O—H⋯O and C—H⋯N hydrogen bonds, both enclosing an S(6) ring motif. In the crystal, mol­ecules stack along the c-axis direction, forming columns within which there are a number of π–π inter­actions [the inter-centroid distances vary from 3.5278 (10) to 3.8625 (10) Å]. The columns are linked by C—H⋯π inter­actions, forming slabs parallel to (100).
format Online
Article
Text
id pubmed-4518926
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-45189262015-08-14 Crystal structure of (2-hy­droxy-5-methyl­phen­yl)(3-methyl-1-phenyl-1H-pyrazolo­[3,4-b]pyridin-5-yl)methanone Raja, Rajamani Poomathi, Nataraj Perumal, Paramasivam T. SubbiahPandi, A. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(21)H(17)N(3)O(2), the 2-hy­droxy-5-methyl­phenyl ring and the phenyl ring are inclined to the mean plane of the pyrazolo­pyridine moiety (r.m.s. deviation = 0.013 Å) by 52.89 (9) and 19.63 (8)°, respectively, and to each other by 42.83 (11)°. In the mol­ecule, there are intra­molecular O—H⋯O and C—H⋯N hydrogen bonds, both enclosing an S(6) ring motif. In the crystal, mol­ecules stack along the c-axis direction, forming columns within which there are a number of π–π inter­actions [the inter-centroid distances vary from 3.5278 (10) to 3.8625 (10) Å]. The columns are linked by C—H⋯π inter­actions, forming slabs parallel to (100). International Union of Crystallography 2015-06-24 /pmc/articles/PMC4518926/ /pubmed/26279931 http://dx.doi.org/10.1107/S2056989015011597 Text en © Raja et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Raja, Rajamani
Poomathi, Nataraj
Perumal, Paramasivam T.
SubbiahPandi, A.
Crystal structure of (2-hy­droxy-5-methyl­phen­yl)(3-methyl-1-phenyl-1H-pyrazolo­[3,4-b]pyridin-5-yl)methanone
title Crystal structure of (2-hy­droxy-5-methyl­phen­yl)(3-methyl-1-phenyl-1H-pyrazolo­[3,4-b]pyridin-5-yl)methanone
title_full Crystal structure of (2-hy­droxy-5-methyl­phen­yl)(3-methyl-1-phenyl-1H-pyrazolo­[3,4-b]pyridin-5-yl)methanone
title_fullStr Crystal structure of (2-hy­droxy-5-methyl­phen­yl)(3-methyl-1-phenyl-1H-pyrazolo­[3,4-b]pyridin-5-yl)methanone
title_full_unstemmed Crystal structure of (2-hy­droxy-5-methyl­phen­yl)(3-methyl-1-phenyl-1H-pyrazolo­[3,4-b]pyridin-5-yl)methanone
title_short Crystal structure of (2-hy­droxy-5-methyl­phen­yl)(3-methyl-1-phenyl-1H-pyrazolo­[3,4-b]pyridin-5-yl)methanone
title_sort crystal structure of (2-hy­droxy-5-methyl­phen­yl)(3-methyl-1-phenyl-1h-pyrazolo­[3,4-b]pyridin-5-yl)methanone
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518926/
https://www.ncbi.nlm.nih.gov/pubmed/26279931
http://dx.doi.org/10.1107/S2056989015011597
work_keys_str_mv AT rajarajamani crystalstructureof2hydroxy5methylphenyl3methyl1phenyl1hpyrazolo34bpyridin5ylmethanone
AT poomathinataraj crystalstructureof2hydroxy5methylphenyl3methyl1phenyl1hpyrazolo34bpyridin5ylmethanone
AT perumalparamasivamt crystalstructureof2hydroxy5methylphenyl3methyl1phenyl1hpyrazolo34bpyridin5ylmethanone
AT subbiahpandia crystalstructureof2hydroxy5methylphenyl3methyl1phenyl1hpyrazolo34bpyridin5ylmethanone