Crystal structure of ethyl 4-(2-meth­oxy­phen­yl)-6-methyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­pyrimidine-5-carboxyl­ate

In the title compound, C(15)H(18)N(2)O(3)S, the hydro­pyrimidine ring adopts a sofa conformation with the methine C atom as the flap. The benzene ring is almost perpendicular to the mean plane of the hydro­pyrimidine ring, making a dihedral angle of 85.51 (8)°, and the meth­oxy O atom lies over the...

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Autores principales: Mohamed, Shaaban K., Mague, Joel T., Akkurt, Mehmet, Khodairy, Ahmed, Ahmed, Eman A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518927/
https://www.ncbi.nlm.nih.gov/pubmed/26279898
http://dx.doi.org/10.1107/S2056989015010026
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author Mohamed, Shaaban K.
Mague, Joel T.
Akkurt, Mehmet
Khodairy, Ahmed
Ahmed, Eman A.
author_facet Mohamed, Shaaban K.
Mague, Joel T.
Akkurt, Mehmet
Khodairy, Ahmed
Ahmed, Eman A.
author_sort Mohamed, Shaaban K.
collection PubMed
description In the title compound, C(15)H(18)N(2)O(3)S, the hydro­pyrimidine ring adopts a sofa conformation with the methine C atom as the flap. The benzene ring is almost perpendicular to the mean plane of the hydro­pyrimidine ring, making a dihedral angle of 85.51 (8)°, and the meth­oxy O atom lies over the centre of the pyrimidine ring. In the crystal, weak N—H⋯S inter­actions form a zigzag chain running along the b-axis direction.
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spelling pubmed-45189272015-08-14 Crystal structure of ethyl 4-(2-meth­oxy­phen­yl)-6-methyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­pyrimidine-5-carboxyl­ate Mohamed, Shaaban K. Mague, Joel T. Akkurt, Mehmet Khodairy, Ahmed Ahmed, Eman A. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(15)H(18)N(2)O(3)S, the hydro­pyrimidine ring adopts a sofa conformation with the methine C atom as the flap. The benzene ring is almost perpendicular to the mean plane of the hydro­pyrimidine ring, making a dihedral angle of 85.51 (8)°, and the meth­oxy O atom lies over the centre of the pyrimidine ring. In the crystal, weak N—H⋯S inter­actions form a zigzag chain running along the b-axis direction. International Union of Crystallography 2015-06-03 /pmc/articles/PMC4518927/ /pubmed/26279898 http://dx.doi.org/10.1107/S2056989015010026 Text en © Mohamed et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Mohamed, Shaaban K.
Mague, Joel T.
Akkurt, Mehmet
Khodairy, Ahmed
Ahmed, Eman A.
Crystal structure of ethyl 4-(2-meth­oxy­phen­yl)-6-methyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­pyrimidine-5-carboxyl­ate
title Crystal structure of ethyl 4-(2-meth­oxy­phen­yl)-6-methyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­pyrimidine-5-carboxyl­ate
title_full Crystal structure of ethyl 4-(2-meth­oxy­phen­yl)-6-methyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­pyrimidine-5-carboxyl­ate
title_fullStr Crystal structure of ethyl 4-(2-meth­oxy­phen­yl)-6-methyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­pyrimidine-5-carboxyl­ate
title_full_unstemmed Crystal structure of ethyl 4-(2-meth­oxy­phen­yl)-6-methyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­pyrimidine-5-carboxyl­ate
title_short Crystal structure of ethyl 4-(2-meth­oxy­phen­yl)-6-methyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­pyrimidine-5-carboxyl­ate
title_sort crystal structure of ethyl 4-(2-meth­oxy­phen­yl)-6-methyl-2-sulfanyl­idene-1,2,3,4-tetra­hydro­pyrimidine-5-carboxyl­ate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518927/
https://www.ncbi.nlm.nih.gov/pubmed/26279898
http://dx.doi.org/10.1107/S2056989015010026
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