Crystal structure of 3,9,9-trimethyl-2,3,3a,4,9,9a-hexa­hydro-1H-cyclo­penta[b]quinolin-4-ium chloride

The title mol­ecular salt, C(15)H(22)N(+)·Cl(−), arose as an unexpected product of the reaction between aniline and melanol in the presence of HCl. The central heterocyclic ring has a half-chair conformation and the five-membered ring has an envelope conformation, with the C atom linked to the N ato...

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Autores principales: Sridhar, G., Bilal, I. Mohammed, Easwaramoorthy, D., Rani, S. Kutti, Solomon, K. Anand
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518934/
https://www.ncbi.nlm.nih.gov/pubmed/26279944
http://dx.doi.org/10.1107/S2056989015011858
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author Sridhar, G.
Bilal, I. Mohammed
Easwaramoorthy, D.
Rani, S. Kutti
Solomon, K. Anand
author_facet Sridhar, G.
Bilal, I. Mohammed
Easwaramoorthy, D.
Rani, S. Kutti
Solomon, K. Anand
author_sort Sridhar, G.
collection PubMed
description The title mol­ecular salt, C(15)H(22)N(+)·Cl(−), arose as an unexpected product of the reaction between aniline and melanol in the presence of HCl. The central heterocyclic ring has a half-chair conformation and the five-membered ring has an envelope conformation, with the C atom linked to the N atom as the flap. In the crystal, the ions are linked by N—H⋯Cl hydrogen bonds, generating chains propagating in the [100] direction. The crystal studied was a merohedral twin with a 0.64 (3):0.36 (3) domain ratio.
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spelling pubmed-45189342015-08-14 Crystal structure of 3,9,9-trimethyl-2,3,3a,4,9,9a-hexa­hydro-1H-cyclo­penta[b]quinolin-4-ium chloride Sridhar, G. Bilal, I. Mohammed Easwaramoorthy, D. Rani, S. Kutti Solomon, K. Anand Acta Crystallogr E Crystallogr Commun Data Reports The title mol­ecular salt, C(15)H(22)N(+)·Cl(−), arose as an unexpected product of the reaction between aniline and melanol in the presence of HCl. The central heterocyclic ring has a half-chair conformation and the five-membered ring has an envelope conformation, with the C atom linked to the N atom as the flap. In the crystal, the ions are linked by N—H⋯Cl hydrogen bonds, generating chains propagating in the [100] direction. The crystal studied was a merohedral twin with a 0.64 (3):0.36 (3) domain ratio. International Union of Crystallography 2015-06-27 /pmc/articles/PMC4518934/ /pubmed/26279944 http://dx.doi.org/10.1107/S2056989015011858 Text en © Sridhar et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Sridhar, G.
Bilal, I. Mohammed
Easwaramoorthy, D.
Rani, S. Kutti
Solomon, K. Anand
Crystal structure of 3,9,9-trimethyl-2,3,3a,4,9,9a-hexa­hydro-1H-cyclo­penta[b]quinolin-4-ium chloride
title Crystal structure of 3,9,9-trimethyl-2,3,3a,4,9,9a-hexa­hydro-1H-cyclo­penta[b]quinolin-4-ium chloride
title_full Crystal structure of 3,9,9-trimethyl-2,3,3a,4,9,9a-hexa­hydro-1H-cyclo­penta[b]quinolin-4-ium chloride
title_fullStr Crystal structure of 3,9,9-trimethyl-2,3,3a,4,9,9a-hexa­hydro-1H-cyclo­penta[b]quinolin-4-ium chloride
title_full_unstemmed Crystal structure of 3,9,9-trimethyl-2,3,3a,4,9,9a-hexa­hydro-1H-cyclo­penta[b]quinolin-4-ium chloride
title_short Crystal structure of 3,9,9-trimethyl-2,3,3a,4,9,9a-hexa­hydro-1H-cyclo­penta[b]quinolin-4-ium chloride
title_sort crystal structure of 3,9,9-trimethyl-2,3,3a,4,9,9a-hexa­hydro-1h-cyclo­penta[b]quinolin-4-ium chloride
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518934/
https://www.ncbi.nlm.nih.gov/pubmed/26279944
http://dx.doi.org/10.1107/S2056989015011858
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