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Crystal structure of ortho­rhom­bic {bis­[(pyridin-2-yl)meth­yl](3,5,5,5-tetra­chloro­pent­yl)amine-κ(3) N,N′,N′′}chlorido­copper(II) perchlorate

In the title compound, [CuCl(C(17)H(19)Cl(4)N(3))]ClO(4), the Cu(II) ion adopts a distorted square-planar geometry defined by one chloride ligand and the three nitro­gen atoms from the bis­[(pyridin-2-yl)meth­yl](3,5,5,5-tetra­chloro­pent­yl)amine ligand. The perchlorate counter-ion is disordered ov...

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Detalles Bibliográficos
Autores principales: Bussey, Katherine A., Cavalier, Annie R., Connell, Jennifer R., Mraz, Margaret E., Oshin, Kayode D., Pintauer, Tomislav, Gray, Danielle L., Parkin, Sean
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518935/
https://www.ncbi.nlm.nih.gov/pubmed/26279883
http://dx.doi.org/10.1107/S2056989015011792
Descripción
Sumario:In the title compound, [CuCl(C(17)H(19)Cl(4)N(3))]ClO(4), the Cu(II) ion adopts a distorted square-planar geometry defined by one chloride ligand and the three nitro­gen atoms from the bis­[(pyridin-2-yl)meth­yl](3,5,5,5-tetra­chloro­pent­yl)amine ligand. The perchlorate counter-ion is disordered over three sets of sites with refined occupancies 0.0634 (17), 0.221 (16) and 0.145 (7). In addition, the hetero-scorpionate arm of the bis­[(pyridin-2-yl)meth­yl](3,5,5,5-tetra­chloro­pent­yl)amine ligand is disordered over two sets of sites with refined occupancies 0.839 (2) and 0.161 (2). In the crystal, weak Cu⋯Cl inter­actions between symmetry-related mol­ecules create a dimerization with a chloride occupying the apical position of the square-pyramidal geometry typical of many copper(II) chloride hetero-scorpionate complexes.