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Crystal structure of ortho­rhom­bic {bis­[(pyridin-2-yl)meth­yl](3,5,5,5-tetra­chloro­pent­yl)amine-κ(3) N,N′,N′′}chlorido­copper(II) perchlorate

In the title compound, [CuCl(C(17)H(19)Cl(4)N(3))]ClO(4), the Cu(II) ion adopts a distorted square-planar geometry defined by one chloride ligand and the three nitro­gen atoms from the bis­[(pyridin-2-yl)meth­yl](3,5,5,5-tetra­chloro­pent­yl)amine ligand. The perchlorate counter-ion is disordered ov...

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Autores principales: Bussey, Katherine A., Cavalier, Annie R., Connell, Jennifer R., Mraz, Margaret E., Oshin, Kayode D., Pintauer, Tomislav, Gray, Danielle L., Parkin, Sean
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518935/
https://www.ncbi.nlm.nih.gov/pubmed/26279883
http://dx.doi.org/10.1107/S2056989015011792
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author Bussey, Katherine A.
Cavalier, Annie R.
Connell, Jennifer R.
Mraz, Margaret E.
Oshin, Kayode D.
Pintauer, Tomislav
Gray, Danielle L.
Parkin, Sean
author_facet Bussey, Katherine A.
Cavalier, Annie R.
Connell, Jennifer R.
Mraz, Margaret E.
Oshin, Kayode D.
Pintauer, Tomislav
Gray, Danielle L.
Parkin, Sean
author_sort Bussey, Katherine A.
collection PubMed
description In the title compound, [CuCl(C(17)H(19)Cl(4)N(3))]ClO(4), the Cu(II) ion adopts a distorted square-planar geometry defined by one chloride ligand and the three nitro­gen atoms from the bis­[(pyridin-2-yl)meth­yl](3,5,5,5-tetra­chloro­pent­yl)amine ligand. The perchlorate counter-ion is disordered over three sets of sites with refined occupancies 0.0634 (17), 0.221 (16) and 0.145 (7). In addition, the hetero-scorpionate arm of the bis­[(pyridin-2-yl)meth­yl](3,5,5,5-tetra­chloro­pent­yl)amine ligand is disordered over two sets of sites with refined occupancies 0.839 (2) and 0.161 (2). In the crystal, weak Cu⋯Cl inter­actions between symmetry-related mol­ecules create a dimerization with a chloride occupying the apical position of the square-pyramidal geometry typical of many copper(II) chloride hetero-scorpionate complexes.
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spelling pubmed-45189352015-08-14 Crystal structure of ortho­rhom­bic {bis­[(pyridin-2-yl)meth­yl](3,5,5,5-tetra­chloro­pent­yl)amine-κ(3) N,N′,N′′}chlorido­copper(II) perchlorate Bussey, Katherine A. Cavalier, Annie R. Connell, Jennifer R. Mraz, Margaret E. Oshin, Kayode D. Pintauer, Tomislav Gray, Danielle L. Parkin, Sean Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [CuCl(C(17)H(19)Cl(4)N(3))]ClO(4), the Cu(II) ion adopts a distorted square-planar geometry defined by one chloride ligand and the three nitro­gen atoms from the bis­[(pyridin-2-yl)meth­yl](3,5,5,5-tetra­chloro­pent­yl)amine ligand. The perchlorate counter-ion is disordered over three sets of sites with refined occupancies 0.0634 (17), 0.221 (16) and 0.145 (7). In addition, the hetero-scorpionate arm of the bis­[(pyridin-2-yl)meth­yl](3,5,5,5-tetra­chloro­pent­yl)amine ligand is disordered over two sets of sites with refined occupancies 0.839 (2) and 0.161 (2). In the crystal, weak Cu⋯Cl inter­actions between symmetry-related mol­ecules create a dimerization with a chloride occupying the apical position of the square-pyramidal geometry typical of many copper(II) chloride hetero-scorpionate complexes. International Union of Crystallography 2015-06-27 /pmc/articles/PMC4518935/ /pubmed/26279883 http://dx.doi.org/10.1107/S2056989015011792 Text en © Bussey et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Bussey, Katherine A.
Cavalier, Annie R.
Connell, Jennifer R.
Mraz, Margaret E.
Oshin, Kayode D.
Pintauer, Tomislav
Gray, Danielle L.
Parkin, Sean
Crystal structure of ortho­rhom­bic {bis­[(pyridin-2-yl)meth­yl](3,5,5,5-tetra­chloro­pent­yl)amine-κ(3) N,N′,N′′}chlorido­copper(II) perchlorate
title Crystal structure of ortho­rhom­bic {bis­[(pyridin-2-yl)meth­yl](3,5,5,5-tetra­chloro­pent­yl)amine-κ(3) N,N′,N′′}chlorido­copper(II) perchlorate
title_full Crystal structure of ortho­rhom­bic {bis­[(pyridin-2-yl)meth­yl](3,5,5,5-tetra­chloro­pent­yl)amine-κ(3) N,N′,N′′}chlorido­copper(II) perchlorate
title_fullStr Crystal structure of ortho­rhom­bic {bis­[(pyridin-2-yl)meth­yl](3,5,5,5-tetra­chloro­pent­yl)amine-κ(3) N,N′,N′′}chlorido­copper(II) perchlorate
title_full_unstemmed Crystal structure of ortho­rhom­bic {bis­[(pyridin-2-yl)meth­yl](3,5,5,5-tetra­chloro­pent­yl)amine-κ(3) N,N′,N′′}chlorido­copper(II) perchlorate
title_short Crystal structure of ortho­rhom­bic {bis­[(pyridin-2-yl)meth­yl](3,5,5,5-tetra­chloro­pent­yl)amine-κ(3) N,N′,N′′}chlorido­copper(II) perchlorate
title_sort crystal structure of ortho­rhom­bic {bis­[(pyridin-2-yl)meth­yl](3,5,5,5-tetra­chloro­pent­yl)amine-κ(3) n,n′,n′′}chlorido­copper(ii) perchlorate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518935/
https://www.ncbi.nlm.nih.gov/pubmed/26279883
http://dx.doi.org/10.1107/S2056989015011792
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