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Crystal structure of orthorhombic {bis[(pyridin-2-yl)methyl](3,5,5,5-tetrachloropentyl)amine-κ(3) N,N′,N′′}chloridocopper(II) perchlorate
In the title compound, [CuCl(C(17)H(19)Cl(4)N(3))]ClO(4), the Cu(II) ion adopts a distorted square-planar geometry defined by one chloride ligand and the three nitrogen atoms from the bis[(pyridin-2-yl)methyl](3,5,5,5-tetrachloropentyl)amine ligand. The perchlorate counter-ion is disordered ov...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518935/ https://www.ncbi.nlm.nih.gov/pubmed/26279883 http://dx.doi.org/10.1107/S2056989015011792 |
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author | Bussey, Katherine A. Cavalier, Annie R. Connell, Jennifer R. Mraz, Margaret E. Oshin, Kayode D. Pintauer, Tomislav Gray, Danielle L. Parkin, Sean |
author_facet | Bussey, Katherine A. Cavalier, Annie R. Connell, Jennifer R. Mraz, Margaret E. Oshin, Kayode D. Pintauer, Tomislav Gray, Danielle L. Parkin, Sean |
author_sort | Bussey, Katherine A. |
collection | PubMed |
description | In the title compound, [CuCl(C(17)H(19)Cl(4)N(3))]ClO(4), the Cu(II) ion adopts a distorted square-planar geometry defined by one chloride ligand and the three nitrogen atoms from the bis[(pyridin-2-yl)methyl](3,5,5,5-tetrachloropentyl)amine ligand. The perchlorate counter-ion is disordered over three sets of sites with refined occupancies 0.0634 (17), 0.221 (16) and 0.145 (7). In addition, the hetero-scorpionate arm of the bis[(pyridin-2-yl)methyl](3,5,5,5-tetrachloropentyl)amine ligand is disordered over two sets of sites with refined occupancies 0.839 (2) and 0.161 (2). In the crystal, weak Cu⋯Cl interactions between symmetry-related molecules create a dimerization with a chloride occupying the apical position of the square-pyramidal geometry typical of many copper(II) chloride hetero-scorpionate complexes. |
format | Online Article Text |
id | pubmed-4518935 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-45189352015-08-14 Crystal structure of orthorhombic {bis[(pyridin-2-yl)methyl](3,5,5,5-tetrachloropentyl)amine-κ(3) N,N′,N′′}chloridocopper(II) perchlorate Bussey, Katherine A. Cavalier, Annie R. Connell, Jennifer R. Mraz, Margaret E. Oshin, Kayode D. Pintauer, Tomislav Gray, Danielle L. Parkin, Sean Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [CuCl(C(17)H(19)Cl(4)N(3))]ClO(4), the Cu(II) ion adopts a distorted square-planar geometry defined by one chloride ligand and the three nitrogen atoms from the bis[(pyridin-2-yl)methyl](3,5,5,5-tetrachloropentyl)amine ligand. The perchlorate counter-ion is disordered over three sets of sites with refined occupancies 0.0634 (17), 0.221 (16) and 0.145 (7). In addition, the hetero-scorpionate arm of the bis[(pyridin-2-yl)methyl](3,5,5,5-tetrachloropentyl)amine ligand is disordered over two sets of sites with refined occupancies 0.839 (2) and 0.161 (2). In the crystal, weak Cu⋯Cl interactions between symmetry-related molecules create a dimerization with a chloride occupying the apical position of the square-pyramidal geometry typical of many copper(II) chloride hetero-scorpionate complexes. International Union of Crystallography 2015-06-27 /pmc/articles/PMC4518935/ /pubmed/26279883 http://dx.doi.org/10.1107/S2056989015011792 Text en © Bussey et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Bussey, Katherine A. Cavalier, Annie R. Connell, Jennifer R. Mraz, Margaret E. Oshin, Kayode D. Pintauer, Tomislav Gray, Danielle L. Parkin, Sean Crystal structure of orthorhombic {bis[(pyridin-2-yl)methyl](3,5,5,5-tetrachloropentyl)amine-κ(3) N,N′,N′′}chloridocopper(II) perchlorate |
title | Crystal structure of orthorhombic {bis[(pyridin-2-yl)methyl](3,5,5,5-tetrachloropentyl)amine-κ(3)
N,N′,N′′}chloridocopper(II) perchlorate |
title_full | Crystal structure of orthorhombic {bis[(pyridin-2-yl)methyl](3,5,5,5-tetrachloropentyl)amine-κ(3)
N,N′,N′′}chloridocopper(II) perchlorate |
title_fullStr | Crystal structure of orthorhombic {bis[(pyridin-2-yl)methyl](3,5,5,5-tetrachloropentyl)amine-κ(3)
N,N′,N′′}chloridocopper(II) perchlorate |
title_full_unstemmed | Crystal structure of orthorhombic {bis[(pyridin-2-yl)methyl](3,5,5,5-tetrachloropentyl)amine-κ(3)
N,N′,N′′}chloridocopper(II) perchlorate |
title_short | Crystal structure of orthorhombic {bis[(pyridin-2-yl)methyl](3,5,5,5-tetrachloropentyl)amine-κ(3)
N,N′,N′′}chloridocopper(II) perchlorate |
title_sort | crystal structure of orthorhombic {bis[(pyridin-2-yl)methyl](3,5,5,5-tetrachloropentyl)amine-κ(3)
n,n′,n′′}chloridocopper(ii) perchlorate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518935/ https://www.ncbi.nlm.nih.gov/pubmed/26279883 http://dx.doi.org/10.1107/S2056989015011792 |
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