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Crystal structure of 3,4-di­chloro­anilinium hydrogen phthalate

In the title salt, C(6)H(6)Cl(2)N(+)·C(8)H(5)O(4) (−), the carb­oxy­lic acid and carboxyl­ate groups of the anion form dihedral angles of 20.79 (19) and 74.76 (14)°, respectively, with the plane of the benzene ring. In the crystal, mol­ecules are assembled into a two-dimensional polymeric network pa...

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Autores principales: Shahid, Muhammad, Tahir, Muhammad Nawaz, Salim, Muhammad, Munawar, Munawar Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518937/
https://www.ncbi.nlm.nih.gov/pubmed/26279899
http://dx.doi.org/10.1107/S2056989015010300
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author Shahid, Muhammad
Tahir, Muhammad Nawaz
Salim, Muhammad
Munawar, Munawar Ali
author_facet Shahid, Muhammad
Tahir, Muhammad Nawaz
Salim, Muhammad
Munawar, Munawar Ali
author_sort Shahid, Muhammad
collection PubMed
description In the title salt, C(6)H(6)Cl(2)N(+)·C(8)H(5)O(4) (−), the carb­oxy­lic acid and carboxyl­ate groups of the anion form dihedral angles of 20.79 (19) and 74.76 (14)°, respectively, with the plane of the benzene ring. In the crystal, mol­ecules are assembled into a two-dimensional polymeric network parallel to (100) via N—H⋯O and O—H⋯O hydrogen bonds. In addition, within the layer, there are π–π stacking inter­actions between the benzene rings of the cation and the anion [centroid–centroid distance = 3.6794 (17) Å]. A weak C—H⋯O interaction is also observed.
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spelling pubmed-45189372015-08-14 Crystal structure of 3,4-di­chloro­anilinium hydrogen phthalate Shahid, Muhammad Tahir, Muhammad Nawaz Salim, Muhammad Munawar, Munawar Ali Acta Crystallogr E Crystallogr Commun Data Reports In the title salt, C(6)H(6)Cl(2)N(+)·C(8)H(5)O(4) (−), the carb­oxy­lic acid and carboxyl­ate groups of the anion form dihedral angles of 20.79 (19) and 74.76 (14)°, respectively, with the plane of the benzene ring. In the crystal, mol­ecules are assembled into a two-dimensional polymeric network parallel to (100) via N—H⋯O and O—H⋯O hydrogen bonds. In addition, within the layer, there are π–π stacking inter­actions between the benzene rings of the cation and the anion [centroid–centroid distance = 3.6794 (17) Å]. A weak C—H⋯O interaction is also observed. International Union of Crystallography 2015-06-03 /pmc/articles/PMC4518937/ /pubmed/26279899 http://dx.doi.org/10.1107/S2056989015010300 Text en © Shahid et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Shahid, Muhammad
Tahir, Muhammad Nawaz
Salim, Muhammad
Munawar, Munawar Ali
Crystal structure of 3,4-di­chloro­anilinium hydrogen phthalate
title Crystal structure of 3,4-di­chloro­anilinium hydrogen phthalate
title_full Crystal structure of 3,4-di­chloro­anilinium hydrogen phthalate
title_fullStr Crystal structure of 3,4-di­chloro­anilinium hydrogen phthalate
title_full_unstemmed Crystal structure of 3,4-di­chloro­anilinium hydrogen phthalate
title_short Crystal structure of 3,4-di­chloro­anilinium hydrogen phthalate
title_sort crystal structure of 3,4-di­chloro­anilinium hydrogen phthalate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518937/
https://www.ncbi.nlm.nih.gov/pubmed/26279899
http://dx.doi.org/10.1107/S2056989015010300
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