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Crystal structure of ethyl 2-(2,4,5-tri­meth­oxy­phen­yl)quinoline-4-carboxyl­ate

In the title compound, C(21)H(21)NO(5), the dihedral angle between the quinoline ring system (r.m.s. deviation = 0.028 Å) and the tri­meth­oxy­benzene ring is 43.38 (5)°. The C atoms of the meth­oxy groups deviate from their attached benzene ring by −0.396 (2), −0.049 (2) and 0.192 (2) Å for the ort...

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Detalles Bibliográficos
Autores principales: Shrungesh Kumar, T. O., Naveen, S., Kumara, M. N., Mahadevan, K. M., Lokanath, N. K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518944/
https://www.ncbi.nlm.nih.gov/pubmed/26279938
http://dx.doi.org/10.1107/S2056989015011706
Descripción
Sumario:In the title compound, C(21)H(21)NO(5), the dihedral angle between the quinoline ring system (r.m.s. deviation = 0.028 Å) and the tri­meth­oxy­benzene ring is 43.38 (5)°. The C atoms of the meth­oxy groups deviate from their attached benzene ring by −0.396 (2), −0.049 (2) and 0.192 (2) Å for the ortho-, meta- and para-substituents, respectively. The pendant ethyl chain is disordered over two orientations in a 0.527 (5):0.473 (5) ratio. A short intra­molecular C—H⋯O contact closes an S(6) ring. In the crystal, inversion dimers linked by pairs of weak C—H⋯O inter­actions generate R (2) (2)(6) loops. The dimers are linked by further C—H⋯O inter­actions to generate [1-10] chains.