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Crystal structure of ethyl 2-(2,4,5-trimethoxyphenyl)quinoline-4-carboxylate
In the title compound, C(21)H(21)NO(5), the dihedral angle between the quinoline ring system (r.m.s. deviation = 0.028 Å) and the trimethoxybenzene ring is 43.38 (5)°. The C atoms of the methoxy groups deviate from their attached benzene ring by −0.396 (2), −0.049 (2) and 0.192 (2) Å for the ort...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518944/ https://www.ncbi.nlm.nih.gov/pubmed/26279938 http://dx.doi.org/10.1107/S2056989015011706 |
Sumario: | In the title compound, C(21)H(21)NO(5), the dihedral angle between the quinoline ring system (r.m.s. deviation = 0.028 Å) and the trimethoxybenzene ring is 43.38 (5)°. The C atoms of the methoxy groups deviate from their attached benzene ring by −0.396 (2), −0.049 (2) and 0.192 (2) Å for the ortho-, meta- and para-substituents, respectively. The pendant ethyl chain is disordered over two orientations in a 0.527 (5):0.473 (5) ratio. A short intramolecular C—H⋯O contact closes an S(6) ring. In the crystal, inversion dimers linked by pairs of weak C—H⋯O interactions generate R (2) (2)(6) loops. The dimers are linked by further C—H⋯O interactions to generate [1-10] chains. |
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