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Crystal structure of 2-(4-tert-butylphenyl)-3-hydroxy-4H-chromen-4-one
Yellow–green fluorescent crystals of the title compound, C(19)H(18)O(3), were obtained by the reaction of hydroxyacetophenone and 4-tert-butylbenzaldehyde with hydrogen peroxide as oxidant. The plane of the benzene ring is slightly twisted to the mean plane of the 4H-chromene-4-one moiety (r.m.s...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518945/ https://www.ncbi.nlm.nih.gov/pubmed/26279877 http://dx.doi.org/10.1107/S2056989015011482 |
Sumario: | Yellow–green fluorescent crystals of the title compound, C(19)H(18)O(3), were obtained by the reaction of hydroxyacetophenone and 4-tert-butylbenzaldehyde with hydrogen peroxide as oxidant. The plane of the benzene ring is slightly twisted to the mean plane of the 4H-chromene-4-one moiety (r.m.s. deviation = 0.0191 Å) by 10.53 (8)°. In the crystal, molecules are linked by pairs of O—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(10) ring motif. The dimers are linked via C—H⋯π interactions, forming sheets parallel to (10-1). |
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