Crystal structure of a new homochiral one-dimensional zincophosphate containing l-me­thio­nine

catena-Poly[[(l-me­thio­nine-κO)zinc]-μ(3)-(hydrogen phosphato)-κ(3) O:O′:O′′], [Zn{PO(3)(OH)}(C(5)H(11)NO(2)S)](n), a new one-dimensional homochiral zincophos­phate, was hydro­thermally synthesized using l-me­thio­nine as a structure-directing agent. The compound consists of a network of ZnO(4) and...

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Autores principales: Chouat, Nadjet, Hasnaoui, Mohammed Abdelkrim, Sassi, Mohamed, Bengueddach, Abdelkader, Lusvardi, Gigliola, Cornia, Andrea
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518946/
https://www.ncbi.nlm.nih.gov/pubmed/26279879
http://dx.doi.org/10.1107/S2056989015011561
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author Chouat, Nadjet
Hasnaoui, Mohammed Abdelkrim
Sassi, Mohamed
Bengueddach, Abdelkader
Lusvardi, Gigliola
Cornia, Andrea
author_facet Chouat, Nadjet
Hasnaoui, Mohammed Abdelkrim
Sassi, Mohamed
Bengueddach, Abdelkader
Lusvardi, Gigliola
Cornia, Andrea
author_sort Chouat, Nadjet
collection PubMed
description catena-Poly[[(l-me­thio­nine-κO)zinc]-μ(3)-(hydrogen phosphato)-κ(3) O:O′:O′′], [Zn{PO(3)(OH)}(C(5)H(11)NO(2)S)](n), a new one-dimensional homochiral zincophos­phate, was hydro­thermally synthesized using l-me­thio­nine as a structure-directing agent. The compound consists of a network of ZnO(4) and (HO)PO(3) tetra­hedra that form ladder-like chains of edge-fused Zn(2)P(2)O(4) rings propagating parallel to [100]. The chains are decorated on each side by zwitterionic l-me­thio­nine ligands, which inter­act with the inorganic framework via Zn—O coordination bonds. The structure displays inter­chain N—H⋯O and O—H⋯S hydrogen bonds.
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spelling pubmed-45189462015-08-14 Crystal structure of a new homochiral one-dimensional zincophosphate containing l-me­thio­nine Chouat, Nadjet Hasnaoui, Mohammed Abdelkrim Sassi, Mohamed Bengueddach, Abdelkader Lusvardi, Gigliola Cornia, Andrea Acta Crystallogr E Crystallogr Commun Research Communications catena-Poly[[(l-me­thio­nine-κO)zinc]-μ(3)-(hydrogen phosphato)-κ(3) O:O′:O′′], [Zn{PO(3)(OH)}(C(5)H(11)NO(2)S)](n), a new one-dimensional homochiral zincophos­phate, was hydro­thermally synthesized using l-me­thio­nine as a structure-directing agent. The compound consists of a network of ZnO(4) and (HO)PO(3) tetra­hedra that form ladder-like chains of edge-fused Zn(2)P(2)O(4) rings propagating parallel to [100]. The chains are decorated on each side by zwitterionic l-me­thio­nine ligands, which inter­act with the inorganic framework via Zn—O coordination bonds. The structure displays inter­chain N—H⋯O and O—H⋯S hydrogen bonds. International Union of Crystallography 2015-06-24 /pmc/articles/PMC4518946/ /pubmed/26279879 http://dx.doi.org/10.1107/S2056989015011561 Text en © Chouat et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Chouat, Nadjet
Hasnaoui, Mohammed Abdelkrim
Sassi, Mohamed
Bengueddach, Abdelkader
Lusvardi, Gigliola
Cornia, Andrea
Crystal structure of a new homochiral one-dimensional zincophosphate containing l-me­thio­nine
title Crystal structure of a new homochiral one-dimensional zincophosphate containing l-me­thio­nine
title_full Crystal structure of a new homochiral one-dimensional zincophosphate containing l-me­thio­nine
title_fullStr Crystal structure of a new homochiral one-dimensional zincophosphate containing l-me­thio­nine
title_full_unstemmed Crystal structure of a new homochiral one-dimensional zincophosphate containing l-me­thio­nine
title_short Crystal structure of a new homochiral one-dimensional zincophosphate containing l-me­thio­nine
title_sort crystal structure of a new homochiral one-dimensional zincophosphate containing l-me­thio­nine
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518946/
https://www.ncbi.nlm.nih.gov/pubmed/26279879
http://dx.doi.org/10.1107/S2056989015011561
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