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Crystal structure of 1,4-diethoxy-9,10-anthraquinone
The asymmetric unit of the title compound, C(18)H(16)O(4), contains two crystallographically independent molecules. The anthraquinone ring systems are slightly bent with dihedral angles of 2.33 (8) and 13.31 (9)° between the two terminal benzene rings. In the crystal, the two independent molecule...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518951/ https://www.ncbi.nlm.nih.gov/pubmed/26279933 http://dx.doi.org/10.1107/S2056989015011901 |
Sumario: | The asymmetric unit of the title compound, C(18)H(16)O(4), contains two crystallographically independent molecules. The anthraquinone ring systems are slightly bent with dihedral angles of 2.33 (8) and 13.31 (9)° between the two terminal benzene rings. In the crystal, the two independent molecules adopt slipped-parallel π-overlap with an average interplanar distance of 3.45 Å, forming a dimer; the centroid–centroid distances of the π–π interactions are 3.6659 (15)–3.8987 (15) Å. The molecules are also linked by C—H⋯O interactions, forming a tape structure along the a-axis direction. The crystal packing is characterized by a dimer-herringbone pattern. |
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