Crystal structure of 2-{[2-meth­oxy-5-(tri­fluoro­meth­yl)phen­yl]iminomethyl}-4-nitro­phenol

In the title compound, C(15)H(11)F(3)N(2)O(4), the N=C bond of the central imine group adopts an E conformation. The dihedral angle between two benzene rings is 6.2 (2)°. There is an intra­molecular bifurcated O—H⋯(N,O) hydrogen bond with S(6) and S(9) ring motifs. In the crystal, mol­ecules are lin...

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Detalles Bibliográficos
Autores principales: Karadayı, Nevzat, Şahin, Songül, Köysal, Yavuz, Coşkun, Emine, Büyükgüngör, Orhan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518952/
https://www.ncbi.nlm.nih.gov/pubmed/26279911
http://dx.doi.org/10.1107/S2056989015010129
Descripción
Sumario:In the title compound, C(15)H(11)F(3)N(2)O(4), the N=C bond of the central imine group adopts an E conformation. The dihedral angle between two benzene rings is 6.2 (2)°. There is an intra­molecular bifurcated O—H⋯(N,O) hydrogen bond with S(6) and S(9) ring motifs. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds into a helical chain along the 3(1) screw axis parallel to c. The –CF(3) group shows rotational disorder over two sites, with occupancies of 0.39 (2) and 0.61 (2).

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