Cargando…
Crystal structure of 2-{[2-methoxy-5-(trifluoromethyl)phenyl]iminomethyl}-4-nitrophenol
In the title compound, C(15)H(11)F(3)N(2)O(4), the N=C bond of the central imine group adopts an E conformation. The dihedral angle between two benzene rings is 6.2 (2)°. There is an intramolecular bifurcated O—H⋯(N,O) hydrogen bond with S(6) and S(9) ring motifs. In the crystal, molecules are lin...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2015
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518952/ https://www.ncbi.nlm.nih.gov/pubmed/26279911 http://dx.doi.org/10.1107/S2056989015010129 |
| _version_ | 1782383432650719232 |
|---|---|
| author | Karadayı, Nevzat Şahin, Songül Köysal, Yavuz Coşkun, Emine Büyükgüngör, Orhan |
| author_facet | Karadayı, Nevzat Şahin, Songül Köysal, Yavuz Coşkun, Emine Büyükgüngör, Orhan |
| author_sort | Karadayı, Nevzat |
| collection | PubMed |
| description | In the title compound, C(15)H(11)F(3)N(2)O(4), the N=C bond of the central imine group adopts an E conformation. The dihedral angle between two benzene rings is 6.2 (2)°. There is an intramolecular bifurcated O—H⋯(N,O) hydrogen bond with S(6) and S(9) ring motifs. In the crystal, molecules are linked by C—H⋯O hydrogen bonds into a helical chain along the 3(1) screw axis parallel to c. The –CF(3) group shows rotational disorder over two sites, with occupancies of 0.39 (2) and 0.61 (2). |
| format | Online Article Text |
| id | pubmed-4518952 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2015 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-45189522015-08-14 Crystal structure of 2-{[2-methoxy-5-(trifluoromethyl)phenyl]iminomethyl}-4-nitrophenol Karadayı, Nevzat Şahin, Songül Köysal, Yavuz Coşkun, Emine Büyükgüngör, Orhan Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(15)H(11)F(3)N(2)O(4), the N=C bond of the central imine group adopts an E conformation. The dihedral angle between two benzene rings is 6.2 (2)°. There is an intramolecular bifurcated O—H⋯(N,O) hydrogen bond with S(6) and S(9) ring motifs. In the crystal, molecules are linked by C—H⋯O hydrogen bonds into a helical chain along the 3(1) screw axis parallel to c. The –CF(3) group shows rotational disorder over two sites, with occupancies of 0.39 (2) and 0.61 (2). International Union of Crystallography 2015-06-13 /pmc/articles/PMC4518952/ /pubmed/26279911 http://dx.doi.org/10.1107/S2056989015010129 Text en © Karadayı et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Data Reports Karadayı, Nevzat Şahin, Songül Köysal, Yavuz Coşkun, Emine Büyükgüngör, Orhan Crystal structure of 2-{[2-methoxy-5-(trifluoromethyl)phenyl]iminomethyl}-4-nitrophenol |
| title | Crystal structure of 2-{[2-methoxy-5-(trifluoromethyl)phenyl]iminomethyl}-4-nitrophenol |
| title_full | Crystal structure of 2-{[2-methoxy-5-(trifluoromethyl)phenyl]iminomethyl}-4-nitrophenol |
| title_fullStr | Crystal structure of 2-{[2-methoxy-5-(trifluoromethyl)phenyl]iminomethyl}-4-nitrophenol |
| title_full_unstemmed | Crystal structure of 2-{[2-methoxy-5-(trifluoromethyl)phenyl]iminomethyl}-4-nitrophenol |
| title_short | Crystal structure of 2-{[2-methoxy-5-(trifluoromethyl)phenyl]iminomethyl}-4-nitrophenol |
| title_sort | crystal structure of 2-{[2-methoxy-5-(trifluoromethyl)phenyl]iminomethyl}-4-nitrophenol |
| topic | Data Reports |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518952/ https://www.ncbi.nlm.nih.gov/pubmed/26279911 http://dx.doi.org/10.1107/S2056989015010129 |
| work_keys_str_mv | AT karadayınevzat crystalstructureof22methoxy5trifluoromethylphenyliminomethyl4nitrophenol AT sahinsongul crystalstructureof22methoxy5trifluoromethylphenyliminomethyl4nitrophenol AT koysalyavuz crystalstructureof22methoxy5trifluoromethylphenyliminomethyl4nitrophenol AT coskunemine crystalstructureof22methoxy5trifluoromethylphenyliminomethyl4nitrophenol AT buyukgungororhan crystalstructureof22methoxy5trifluoromethylphenyliminomethyl4nitrophenol |