Crystal structure of 1-[(2,4,6-triiso­propyl­phen­yl)sulfon­yl]aziridine

The title compound, C(17)H(27)NO(2)S, exhibits a distorted geometry of the aromatic ring with elongated bonds at the ipso-C atom. The S atom deviates from the aromatic ring plane by 0.393 (4) Å. Similar to this, the adjacent isopropyl groups are bent out of the aromatic ring plane by −0.125 (4) and...

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Detalles Bibliográficos
Autores principales: Knauer, Lena, Golz, Christopher, Strohmann, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518957/
https://www.ncbi.nlm.nih.gov/pubmed/26279895
http://dx.doi.org/10.1107/S2056989015010221
Descripción
Sumario:The title compound, C(17)H(27)NO(2)S, exhibits a distorted geometry of the aromatic ring with elongated bonds at the ipso-C atom. The S atom deviates from the aromatic ring plane by 0.393 (4) Å. Similar to this, the adjacent isopropyl groups are bent out of the aromatic ring plane by −0.125 (4) and −0.154 (4) Å. Even the distant isopropyl group in para-position to the sulfonyl moiety shows a slight deviation from the ring plane of 0.111 (5) Å. These distortions, which are caused by the bulky substituents, can also be observed in related sulfonyl­aziridine structures.

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