Crystal structure of 1-[(2,4,6-triiso­propyl­phen­yl)sulfon­yl]aziridine

The title compound, C(17)H(27)NO(2)S, exhibits a distorted geometry of the aromatic ring with elongated bonds at the ipso-C atom. The S atom deviates from the aromatic ring plane by 0.393 (4) Å. Similar to this, the adjacent isopropyl groups are bent out of the aromatic ring plane by −0.125 (4) and...

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Detalles Bibliográficos
Autores principales: Knauer, Lena, Golz, Christopher, Strohmann, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518957/
https://www.ncbi.nlm.nih.gov/pubmed/26279895
http://dx.doi.org/10.1107/S2056989015010221
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author Knauer, Lena
Golz, Christopher
Strohmann, Carsten
author_facet Knauer, Lena
Golz, Christopher
Strohmann, Carsten
author_sort Knauer, Lena
collection PubMed
description The title compound, C(17)H(27)NO(2)S, exhibits a distorted geometry of the aromatic ring with elongated bonds at the ipso-C atom. The S atom deviates from the aromatic ring plane by 0.393 (4) Å. Similar to this, the adjacent isopropyl groups are bent out of the aromatic ring plane by −0.125 (4) and −0.154 (4) Å. Even the distant isopropyl group in para-position to the sulfonyl moiety shows a slight deviation from the ring plane of 0.111 (5) Å. These distortions, which are caused by the bulky substituents, can also be observed in related sulfonyl­aziridine structures.
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spelling pubmed-45189572015-08-14 Crystal structure of 1-[(2,4,6-triiso­propyl­phen­yl)sulfon­yl]aziridine Knauer, Lena Golz, Christopher Strohmann, Carsten Acta Crystallogr E Crystallogr Commun Data Reports The title compound, C(17)H(27)NO(2)S, exhibits a distorted geometry of the aromatic ring with elongated bonds at the ipso-C atom. The S atom deviates from the aromatic ring plane by 0.393 (4) Å. Similar to this, the adjacent isopropyl groups are bent out of the aromatic ring plane by −0.125 (4) and −0.154 (4) Å. Even the distant isopropyl group in para-position to the sulfonyl moiety shows a slight deviation from the ring plane of 0.111 (5) Å. These distortions, which are caused by the bulky substituents, can also be observed in related sulfonyl­aziridine structures. International Union of Crystallography 2015-06-03 /pmc/articles/PMC4518957/ /pubmed/26279895 http://dx.doi.org/10.1107/S2056989015010221 Text en © Knauer et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Knauer, Lena
Golz, Christopher
Strohmann, Carsten
Crystal structure of 1-[(2,4,6-triiso­propyl­phen­yl)sulfon­yl]aziridine
title Crystal structure of 1-[(2,4,6-triiso­propyl­phen­yl)sulfon­yl]aziridine
title_full Crystal structure of 1-[(2,4,6-triiso­propyl­phen­yl)sulfon­yl]aziridine
title_fullStr Crystal structure of 1-[(2,4,6-triiso­propyl­phen­yl)sulfon­yl]aziridine
title_full_unstemmed Crystal structure of 1-[(2,4,6-triiso­propyl­phen­yl)sulfon­yl]aziridine
title_short Crystal structure of 1-[(2,4,6-triiso­propyl­phen­yl)sulfon­yl]aziridine
title_sort crystal structure of 1-[(2,4,6-triiso­propyl­phen­yl)sulfon­yl]aziridine
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518957/
https://www.ncbi.nlm.nih.gov/pubmed/26279895
http://dx.doi.org/10.1107/S2056989015010221
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AT golzchristopher crystalstructureof1246triisopropylphenylsulfonylaziridine
AT strohmanncarsten crystalstructureof1246triisopropylphenylsulfonylaziridine

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