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Crystal structure of (6-bromo-2-oxo-2H-chromen-4-yl)methyl morpholine-4-carbodithioate
In the title compound, C(15)H(14)BrNO(3)S(2), the 2H-chromene ring system is nearly planar, with a maximum deviation of 0.034 (2) Å, and the morpholine ring adopts a chair conformation. The dihedral angle between best plane through the 2H-chromene ring system and the morpholine ring is 86.32 (9)°. I...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518962/ https://www.ncbi.nlm.nih.gov/pubmed/26279923 http://dx.doi.org/10.1107/S2056989015011007 |
Sumario: | In the title compound, C(15)H(14)BrNO(3)S(2), the 2H-chromene ring system is nearly planar, with a maximum deviation of 0.034 (2) Å, and the morpholine ring adopts a chair conformation. The dihedral angle between best plane through the 2H-chromene ring system and the morpholine ring is 86.32 (9)°. Intramolecular C—H⋯S hydrogen bonds are observed. In the crystal, inversion-related C—H⋯S and C—H⋯O interactions generate R (2) (2)(10) and R (2) (2)(8) rings patterns, respectively. In addition, the crystal packing features π–π interactions between fused benzene rings [centroid–centroid distance = 3.7558 (12) Å]. |
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