Crystal structure of 6-amino-4-(3-bromo-4-meth­oxy­phen­yl)-3-methyl-2,4-di­hydro­pyrano[2,3-c]pyrazole-5-carbo­nitrile dimethyl sulfoxide monosolvate

In the pyrazole mol­ecule of the title solvate, C(15)H(13)BrN(4)O(2)·C(2)H(6)OS, the dihedral angle between the benzene ring and the mean plane of the di­hydro­pyrano[2,3-c]pyrazole ring system [r.m.s deviation = 0.031 (2) Å] is 86.71 (14)°. In the crystal, the pyrazole mol­ecules are linked by N—H⋯...

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Autores principales: Yousuf, Sammer, Bano, Huma, Muhammad, Munira Taj, Khan, Khalid Mohammed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518963/
https://www.ncbi.nlm.nih.gov/pubmed/26279904
http://dx.doi.org/10.1107/S2056989015010543
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author Yousuf, Sammer
Bano, Huma
Muhammad, Munira Taj
Khan, Khalid Mohammed
author_facet Yousuf, Sammer
Bano, Huma
Muhammad, Munira Taj
Khan, Khalid Mohammed
author_sort Yousuf, Sammer
collection PubMed
description In the pyrazole mol­ecule of the title solvate, C(15)H(13)BrN(4)O(2)·C(2)H(6)OS, the dihedral angle between the benzene ring and the mean plane of the di­hydro­pyrano[2,3-c]pyrazole ring system [r.m.s deviation = 0.031 (2) Å] is 86.71 (14)°. In the crystal, the pyrazole mol­ecules are linked by N—H⋯N hydrogen bonds, forming a layer parallel to (10-1). The pyrazole and dimethyl sulfoxide mol­ecules are connected by an N—H⋯O hydrogen bond.
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spelling pubmed-45189632015-08-14 Crystal structure of 6-amino-4-(3-bromo-4-meth­oxy­phen­yl)-3-methyl-2,4-di­hydro­pyrano[2,3-c]pyrazole-5-carbo­nitrile dimethyl sulfoxide monosolvate Yousuf, Sammer Bano, Huma Muhammad, Munira Taj Khan, Khalid Mohammed Acta Crystallogr E Crystallogr Commun Data Reports In the pyrazole mol­ecule of the title solvate, C(15)H(13)BrN(4)O(2)·C(2)H(6)OS, the dihedral angle between the benzene ring and the mean plane of the di­hydro­pyrano[2,3-c]pyrazole ring system [r.m.s deviation = 0.031 (2) Å] is 86.71 (14)°. In the crystal, the pyrazole mol­ecules are linked by N—H⋯N hydrogen bonds, forming a layer parallel to (10-1). The pyrazole and dimethyl sulfoxide mol­ecules are connected by an N—H⋯O hydrogen bond. International Union of Crystallography 2015-06-06 /pmc/articles/PMC4518963/ /pubmed/26279904 http://dx.doi.org/10.1107/S2056989015010543 Text en © Yousuf et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Yousuf, Sammer
Bano, Huma
Muhammad, Munira Taj
Khan, Khalid Mohammed
Crystal structure of 6-amino-4-(3-bromo-4-meth­oxy­phen­yl)-3-methyl-2,4-di­hydro­pyrano[2,3-c]pyrazole-5-carbo­nitrile dimethyl sulfoxide monosolvate
title Crystal structure of 6-amino-4-(3-bromo-4-meth­oxy­phen­yl)-3-methyl-2,4-di­hydro­pyrano[2,3-c]pyrazole-5-carbo­nitrile dimethyl sulfoxide monosolvate
title_full Crystal structure of 6-amino-4-(3-bromo-4-meth­oxy­phen­yl)-3-methyl-2,4-di­hydro­pyrano[2,3-c]pyrazole-5-carbo­nitrile dimethyl sulfoxide monosolvate
title_fullStr Crystal structure of 6-amino-4-(3-bromo-4-meth­oxy­phen­yl)-3-methyl-2,4-di­hydro­pyrano[2,3-c]pyrazole-5-carbo­nitrile dimethyl sulfoxide monosolvate
title_full_unstemmed Crystal structure of 6-amino-4-(3-bromo-4-meth­oxy­phen­yl)-3-methyl-2,4-di­hydro­pyrano[2,3-c]pyrazole-5-carbo­nitrile dimethyl sulfoxide monosolvate
title_short Crystal structure of 6-amino-4-(3-bromo-4-meth­oxy­phen­yl)-3-methyl-2,4-di­hydro­pyrano[2,3-c]pyrazole-5-carbo­nitrile dimethyl sulfoxide monosolvate
title_sort crystal structure of 6-amino-4-(3-bromo-4-meth­oxy­phen­yl)-3-methyl-2,4-di­hydro­pyrano[2,3-c]pyrazole-5-carbo­nitrile dimethyl sulfoxide monosolvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518963/
https://www.ncbi.nlm.nih.gov/pubmed/26279904
http://dx.doi.org/10.1107/S2056989015010543
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