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Crystal structure of (E)-1-{[(3,5-dimethylphenyl)imino]methyl}naphthalen-2-ol
The title compound, C(19)H(17)NO, has an E conformation about the N=C bond. The molecule is relatively planar, with the benzene ring and naphthalene ring plane being inclined to one another by 4.28 (10)°. There is an intramolecular O—H⋯N hydrogen bond generating an S(6) ring motif. In the crystal,...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518976/ https://www.ncbi.nlm.nih.gov/pubmed/26279928 http://dx.doi.org/10.1107/S2056989015011548 |
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author | Abu-Dief, Ahmed M. Abdelbaky, Mohammed S. M. Garcia-Granda, Santiago |
author_facet | Abu-Dief, Ahmed M. Abdelbaky, Mohammed S. M. Garcia-Granda, Santiago |
author_sort | Abu-Dief, Ahmed M. |
collection | PubMed |
description | The title compound, C(19)H(17)NO, has an E conformation about the N=C bond. The molecule is relatively planar, with the benzene ring and naphthalene ring plane being inclined to one another by 4.28 (10)°. There is an intramolecular O—H⋯N hydrogen bond generating an S(6) ring motif. In the crystal, molecules are linked via C—H⋯O hydrogen bonds, forming chains propagating along [100]. Within the chains there are π–π interactions involving the benzene ring and the naphthalene ring system of an adjacent molecule [inter-centroid distance = 3.6405 (14) Å]. |
format | Online Article Text |
id | pubmed-4518976 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-45189762015-08-14 Crystal structure of (E)-1-{[(3,5-dimethylphenyl)imino]methyl}naphthalen-2-ol Abu-Dief, Ahmed M. Abdelbaky, Mohammed S. M. Garcia-Granda, Santiago Acta Crystallogr E Crystallogr Commun Data Reports The title compound, C(19)H(17)NO, has an E conformation about the N=C bond. The molecule is relatively planar, with the benzene ring and naphthalene ring plane being inclined to one another by 4.28 (10)°. There is an intramolecular O—H⋯N hydrogen bond generating an S(6) ring motif. In the crystal, molecules are linked via C—H⋯O hydrogen bonds, forming chains propagating along [100]. Within the chains there are π–π interactions involving the benzene ring and the naphthalene ring system of an adjacent molecule [inter-centroid distance = 3.6405 (14) Å]. International Union of Crystallography 2015-06-20 /pmc/articles/PMC4518976/ /pubmed/26279928 http://dx.doi.org/10.1107/S2056989015011548 Text en © Abu-Dief et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Abu-Dief, Ahmed M. Abdelbaky, Mohammed S. M. Garcia-Granda, Santiago Crystal structure of (E)-1-{[(3,5-dimethylphenyl)imino]methyl}naphthalen-2-ol |
title | Crystal structure of (E)-1-{[(3,5-dimethylphenyl)imino]methyl}naphthalen-2-ol |
title_full | Crystal structure of (E)-1-{[(3,5-dimethylphenyl)imino]methyl}naphthalen-2-ol |
title_fullStr | Crystal structure of (E)-1-{[(3,5-dimethylphenyl)imino]methyl}naphthalen-2-ol |
title_full_unstemmed | Crystal structure of (E)-1-{[(3,5-dimethylphenyl)imino]methyl}naphthalen-2-ol |
title_short | Crystal structure of (E)-1-{[(3,5-dimethylphenyl)imino]methyl}naphthalen-2-ol |
title_sort | crystal structure of (e)-1-{[(3,5-dimethylphenyl)imino]methyl}naphthalen-2-ol |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518976/ https://www.ncbi.nlm.nih.gov/pubmed/26279928 http://dx.doi.org/10.1107/S2056989015011548 |
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