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Crystal structure of (E)-1-{[(3,5-di­methyl­phen­yl)imino]­meth­yl}naphthalen-2-ol

The title compound, C(19)H(17)NO, has an E conformation about the N=C bond. The mol­ecule is relatively planar, with the benzene ring and naphthalene ring plane being inclined to one another by 4.28 (10)°. There is an intra­molecular O—H⋯N hydrogen bond generating an S(6) ring motif. In the crystal,...

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Detalles Bibliográficos
Autores principales: Abu-Dief, Ahmed M., Abdelbaky, Mohammed S. M., Garcia-Granda, Santiago
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518976/
https://www.ncbi.nlm.nih.gov/pubmed/26279928
http://dx.doi.org/10.1107/S2056989015011548
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author Abu-Dief, Ahmed M.
Abdelbaky, Mohammed S. M.
Garcia-Granda, Santiago
author_facet Abu-Dief, Ahmed M.
Abdelbaky, Mohammed S. M.
Garcia-Granda, Santiago
author_sort Abu-Dief, Ahmed M.
collection PubMed
description The title compound, C(19)H(17)NO, has an E conformation about the N=C bond. The mol­ecule is relatively planar, with the benzene ring and naphthalene ring plane being inclined to one another by 4.28 (10)°. There is an intra­molecular O—H⋯N hydrogen bond generating an S(6) ring motif. In the crystal, mol­ecules are linked via C—H⋯O hydrogen bonds, forming chains propagating along [100]. Within the chains there are π–π inter­actions involving the benzene ring and the naphthalene ring system of an adjacent mol­ecule [inter-centroid distance = 3.6405 (14) Å].
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spelling pubmed-45189762015-08-14 Crystal structure of (E)-1-{[(3,5-di­methyl­phen­yl)imino]­meth­yl}naphthalen-2-ol Abu-Dief, Ahmed M. Abdelbaky, Mohammed S. M. Garcia-Granda, Santiago Acta Crystallogr E Crystallogr Commun Data Reports The title compound, C(19)H(17)NO, has an E conformation about the N=C bond. The mol­ecule is relatively planar, with the benzene ring and naphthalene ring plane being inclined to one another by 4.28 (10)°. There is an intra­molecular O—H⋯N hydrogen bond generating an S(6) ring motif. In the crystal, mol­ecules are linked via C—H⋯O hydrogen bonds, forming chains propagating along [100]. Within the chains there are π–π inter­actions involving the benzene ring and the naphthalene ring system of an adjacent mol­ecule [inter-centroid distance = 3.6405 (14) Å]. International Union of Crystallography 2015-06-20 /pmc/articles/PMC4518976/ /pubmed/26279928 http://dx.doi.org/10.1107/S2056989015011548 Text en © Abu-Dief et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Abu-Dief, Ahmed M.
Abdelbaky, Mohammed S. M.
Garcia-Granda, Santiago
Crystal structure of (E)-1-{[(3,5-di­methyl­phen­yl)imino]­meth­yl}naphthalen-2-ol
title Crystal structure of (E)-1-{[(3,5-di­methyl­phen­yl)imino]­meth­yl}naphthalen-2-ol
title_full Crystal structure of (E)-1-{[(3,5-di­methyl­phen­yl)imino]­meth­yl}naphthalen-2-ol
title_fullStr Crystal structure of (E)-1-{[(3,5-di­methyl­phen­yl)imino]­meth­yl}naphthalen-2-ol
title_full_unstemmed Crystal structure of (E)-1-{[(3,5-di­methyl­phen­yl)imino]­meth­yl}naphthalen-2-ol
title_short Crystal structure of (E)-1-{[(3,5-di­methyl­phen­yl)imino]­meth­yl}naphthalen-2-ol
title_sort crystal structure of (e)-1-{[(3,5-di­methyl­phen­yl)imino]­meth­yl}naphthalen-2-ol
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518976/
https://www.ncbi.nlm.nih.gov/pubmed/26279928
http://dx.doi.org/10.1107/S2056989015011548
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