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Crystal structure of azimsulfuron
The title compound {systematic name: 1-(4,6-dimethoxypyrimidin-2-yl)-3-[1-methyl-4-(2-methyl-2H-tetrazol-5-yl)pyrazol-5-ylsulfonyl]urea}, C(13)H(16)N(10)O(5)S, is a sulfonylurea herbicide. In this compound, the dihedral angles between the planes of the central pyrazole and the terminal dimeth...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518981/ https://www.ncbi.nlm.nih.gov/pubmed/26279913 http://dx.doi.org/10.1107/S2056989015010968 |
Sumario: | The title compound {systematic name: 1-(4,6-dimethoxypyrimidin-2-yl)-3-[1-methyl-4-(2-methyl-2H-tetrazol-5-yl)pyrazol-5-ylsulfonyl]urea}, C(13)H(16)N(10)O(5)S, is a sulfonylurea herbicide. In this compound, the dihedral angles between the planes of the central pyrazole and the terminal dimethoxypyrimidine and tetrazole rings are 79.10 (8) and 17.21 (16)°, respectively. In the crystal, N—H⋯O hydrogen bonds link adjacent molecules, forming R (2) (2)(8) inversion dimers. In addition, weak C—H⋯O and C—H⋯N hydrogen bonds and weak π–π interactions [ring centroid separation = 3.8255 (12) Å] are present, resulting in a three-dimensional architecture. |
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