Crystal structure of (E)-4,4′-(but-2-ene-1,4-di­yl)bis­(2-meth­oxy­phenol)

The title compound, C(18)H(20)O(4), was synthesized via the ruthenium-catalyzed alkene methathesis dimerization of eugenol. The whole mol­ecule is generated by inversion symmetry; the center of inversion being located at the mid-point of the trans C=C bond. The phenol ring is inclined to the mean pl...

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Detalles Bibliográficos
Autores principales: Knight, Kyle S., Carey, Patrick J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518983/
https://www.ncbi.nlm.nih.gov/pubmed/26279930
http://dx.doi.org/10.1107/S2056989015011585
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author Knight, Kyle S.
Carey, Patrick J.
author_facet Knight, Kyle S.
Carey, Patrick J.
author_sort Knight, Kyle S.
collection PubMed
description The title compound, C(18)H(20)O(4), was synthesized via the ruthenium-catalyzed alkene methathesis dimerization of eugenol. The whole mol­ecule is generated by inversion symmetry; the center of inversion being located at the mid-point of the trans C=C bond. The phenol ring is inclined to the mean plane of the central C—C=C—C unit (r.m.s. deviation = 0.014 Å) by 68.83 (16)°. In the crystal, mol­ecules are linked via O—H⋯O hydrogen bonds, involving the hy­droxy and meth­oxy groups, forming undulating sheets parallel to (010).
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spelling pubmed-45189832015-08-14 Crystal structure of (E)-4,4′-(but-2-ene-1,4-di­yl)bis­(2-meth­oxy­phenol) Knight, Kyle S. Carey, Patrick J. Acta Crystallogr E Crystallogr Commun Data Reports The title compound, C(18)H(20)O(4), was synthesized via the ruthenium-catalyzed alkene methathesis dimerization of eugenol. The whole mol­ecule is generated by inversion symmetry; the center of inversion being located at the mid-point of the trans C=C bond. The phenol ring is inclined to the mean plane of the central C—C=C—C unit (r.m.s. deviation = 0.014 Å) by 68.83 (16)°. In the crystal, mol­ecules are linked via O—H⋯O hydrogen bonds, involving the hy­droxy and meth­oxy groups, forming undulating sheets parallel to (010). International Union of Crystallography 2015-06-20 /pmc/articles/PMC4518983/ /pubmed/26279930 http://dx.doi.org/10.1107/S2056989015011585 Text en © Knight and Carey 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Knight, Kyle S.
Carey, Patrick J.
Crystal structure of (E)-4,4′-(but-2-ene-1,4-di­yl)bis­(2-meth­oxy­phenol)
title Crystal structure of (E)-4,4′-(but-2-ene-1,4-di­yl)bis­(2-meth­oxy­phenol)
title_full Crystal structure of (E)-4,4′-(but-2-ene-1,4-di­yl)bis­(2-meth­oxy­phenol)
title_fullStr Crystal structure of (E)-4,4′-(but-2-ene-1,4-di­yl)bis­(2-meth­oxy­phenol)
title_full_unstemmed Crystal structure of (E)-4,4′-(but-2-ene-1,4-di­yl)bis­(2-meth­oxy­phenol)
title_short Crystal structure of (E)-4,4′-(but-2-ene-1,4-di­yl)bis­(2-meth­oxy­phenol)
title_sort crystal structure of (e)-4,4′-(but-2-ene-1,4-di­yl)bis­(2-meth­oxy­phenol)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518983/
https://www.ncbi.nlm.nih.gov/pubmed/26279930
http://dx.doi.org/10.1107/S2056989015011585
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