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Crystal structure of 2-amino-4-phenyl-4H-benzo[h]chromene-3-carbonitrile
In the title compound, C(20)H(14)N(2)O, the plane of the phenyl ring is almost normal to that of the naphthalene ring system, forming a dihedral angle of 83.15 (8)°. The 4H-pyran ring fused with the naphthalene ring system has a flattened boat conformation. In the crystal, molecules are linked by p...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518988/ https://www.ncbi.nlm.nih.gov/pubmed/26279939 http://dx.doi.org/10.1107/S2056989015011536 |
Sumario: | In the title compound, C(20)H(14)N(2)O, the plane of the phenyl ring is almost normal to that of the naphthalene ring system, forming a dihedral angle of 83.15 (8)°. The 4H-pyran ring fused with the naphthalene ring system has a flattened boat conformation. In the crystal, molecules are linked by pairs of N—H⋯N hydrogen bonds, forming inversion dimers with an R (2) (2)(12) ring motif. The dimers are connected by C—H⋯π interactions, forming supramolecular chains along [010]. |
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