Crystal structure of 2-amino-4-phenyl-4H-benzo[h]chromene-3-carbo­nitrile

In the title compound, C(20)H(14)N(2)O, the plane of the phenyl ring is almost normal to that of the naphthalene ring system, forming a dihedral angle of 83.15 (8)°. The 4H-pyran ring fused with the naphthalene ring system has a flattened boat conformation. In the crystal, mol­ecules are linked by p...

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Autores principales: Mohamed, Shaaban K., Horton, Peter N., Akkurt, Mehmet, Younes, Sabry H. H., Albayati, Mustafa R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518988/
https://www.ncbi.nlm.nih.gov/pubmed/26279939
http://dx.doi.org/10.1107/S2056989015011536
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author Mohamed, Shaaban K.
Horton, Peter N.
Akkurt, Mehmet
Younes, Sabry H. H.
Albayati, Mustafa R.
author_facet Mohamed, Shaaban K.
Horton, Peter N.
Akkurt, Mehmet
Younes, Sabry H. H.
Albayati, Mustafa R.
author_sort Mohamed, Shaaban K.
collection PubMed
description In the title compound, C(20)H(14)N(2)O, the plane of the phenyl ring is almost normal to that of the naphthalene ring system, forming a dihedral angle of 83.15 (8)°. The 4H-pyran ring fused with the naphthalene ring system has a flattened boat conformation. In the crystal, mol­ecules are linked by pairs of N—H⋯N hydrogen bonds, forming inversion dimers with an R (2) (2)(12) ring motif. The dimers are connected by C—H⋯π inter­actions, forming supra­molecular chains along [010].
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spelling pubmed-45189882015-08-14 Crystal structure of 2-amino-4-phenyl-4H-benzo[h]chromene-3-carbo­nitrile Mohamed, Shaaban K. Horton, Peter N. Akkurt, Mehmet Younes, Sabry H. H. Albayati, Mustafa R. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(20)H(14)N(2)O, the plane of the phenyl ring is almost normal to that of the naphthalene ring system, forming a dihedral angle of 83.15 (8)°. The 4H-pyran ring fused with the naphthalene ring system has a flattened boat conformation. In the crystal, mol­ecules are linked by pairs of N—H⋯N hydrogen bonds, forming inversion dimers with an R (2) (2)(12) ring motif. The dimers are connected by C—H⋯π inter­actions, forming supra­molecular chains along [010]. International Union of Crystallography 2015-06-27 /pmc/articles/PMC4518988/ /pubmed/26279939 http://dx.doi.org/10.1107/S2056989015011536 Text en © Mohamed et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Mohamed, Shaaban K.
Horton, Peter N.
Akkurt, Mehmet
Younes, Sabry H. H.
Albayati, Mustafa R.
Crystal structure of 2-amino-4-phenyl-4H-benzo[h]chromene-3-carbo­nitrile
title Crystal structure of 2-amino-4-phenyl-4H-benzo[h]chromene-3-carbo­nitrile
title_full Crystal structure of 2-amino-4-phenyl-4H-benzo[h]chromene-3-carbo­nitrile
title_fullStr Crystal structure of 2-amino-4-phenyl-4H-benzo[h]chromene-3-carbo­nitrile
title_full_unstemmed Crystal structure of 2-amino-4-phenyl-4H-benzo[h]chromene-3-carbo­nitrile
title_short Crystal structure of 2-amino-4-phenyl-4H-benzo[h]chromene-3-carbo­nitrile
title_sort crystal structure of 2-amino-4-phenyl-4h-benzo[h]chromene-3-carbo­nitrile
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518988/
https://www.ncbi.nlm.nih.gov/pubmed/26279939
http://dx.doi.org/10.1107/S2056989015011536
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