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Crystal structure of oxadiarg­yl

In the title compound {systematic name: 5-tert-butyl-3-[2,4-di­chloro-5-(prop-2-yn­yloxy)phen­yl]-1,3,4-oxa­diazol-2(3H)-one}, C(15)H(14)Cl(2)N(2)O(3), which is an oxa­diazo­lone herbicide, the dihedral angle between the planes of the oxa­diazo­lone and benzene rings is 65.84 (6)°. In the crystal, w...

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Detalles Bibliográficos
Autores principales: Kang, Gihaeng, Kim, Jineun, Park, Hyunjin, Kim, Tae Ho
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518994/
https://www.ncbi.nlm.nih.gov/pubmed/26279926
http://dx.doi.org/10.1107/S2056989015011524
Descripción
Sumario:In the title compound {systematic name: 5-tert-butyl-3-[2,4-di­chloro-5-(prop-2-yn­yloxy)phen­yl]-1,3,4-oxa­diazol-2(3H)-one}, C(15)H(14)Cl(2)N(2)O(3), which is an oxa­diazo­lone herbicide, the dihedral angle between the planes of the oxa­diazo­lone and benzene rings is 65.84 (6)°. In the crystal, weak inter­molecular Cl⋯Cl [3.3600 (7) Å] short contacts link adjacent mol­ecules, forming chains along the b-axis direction. These chains are linked by C—H⋯O, C—H⋯N and C—H⋯Cl hydrogen bonds, generating a three-dimensional network. Weak C—H⋯π inter­actions are also present.