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Ru-Catalyzed Isomerization Provides Access to Alternating Copolymers via Ring-Opening Metathesis Polymerization
[Image: see text] We describe an isomerization–alternating ROMP protocol that gives linear copolymers with rigorous sequence alternation. Bicyclo[4.2.0]oct-7-ene-7-carboxamides of primary amines are isomerized in the presence of (3-BrPyr)(2)Cl(2)(H(2)IMes)Ru=CHPh to the corresponding bicyclo[4.2.0]o...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2015
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4520717/ https://www.ncbi.nlm.nih.gov/pubmed/26243969 http://dx.doi.org/10.1021/acs.macromol.5b01058 |