Oligosilanylsilatranes

[Image: see text] Oligosilanes with attached silatranyl units were obtained by reactions of potassium oligosilanides with a silatranyl triflate. Interaction between Si and N atoms was observed in the (29)Si NMR spectra (upfield-shifted SiO(3) resonances) and in the solid-state structures (Si–N dista...

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Detalles Bibliográficos
Autores principales: Aghazadeh Meshgi, Mohammad, Baumgartner, Judith, Marschner, Christoph
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4534837/
https://www.ncbi.nlm.nih.gov/pubmed/26294804
http://dx.doi.org/10.1021/acs.organomet.5b00404
Descripción
Sumario:[Image: see text] Oligosilanes with attached silatranyl units were obtained by reactions of potassium oligosilanides with a silatranyl triflate. Interaction between Si and N atoms was observed in the (29)Si NMR spectra (upfield-shifted SiO(3) resonances) and in the solid-state structures (Si–N distances between 2.29 and 2.16 Å). The Si–N interaction can be “switched off” either by protonation of the nitrogen lone pair or by potassium silanide formation caused by trimethylsilyl group cleavage in the presence of potassium tert-butoxide.

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