Halide-Mediated Ortho-Deprotonation Reactions Applied to the Synthesis of 1,2- and 1,3-Disubstituted Ferrocene Derivatives

[Image: see text] The ortho-deprotonation of halide-substituted ferrocenes by treatment with lithium tetramethylpiperidide (LiTMP) has been investigated. Iodo-, bromo-, and chloro-substituted ferrocenes were easily deprotonated adjacent to the halide substituents. The synthetic applicability of this...

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Detalles Bibliográficos
Autores principales: Zirakzadeh, Afrooz, Herlein, Alexander, Groß, Manuela A., Mereiter, Kurt, Wang, Yaping, Weissensteiner, Walter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4534838/
https://www.ncbi.nlm.nih.gov/pubmed/26294806
http://dx.doi.org/10.1021/acs.organomet.5b00464

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4534838/
https://www.ncbi.nlm.nih.gov/pubmed/26294806
http://dx.doi.org/10.1021/acs.organomet.5b00464

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