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On the Question of Site-Selective Ligand Exchange in Carboxylate-Substituted Metal Oxo Clusters
Reaction of [Ti(4)Zr(4)O(6)(OBu)(4)(OMc)(16)] (OMc = methacrylate) with acetylacetone (acacH) resulted in dissection of the cluster and formation of [Ti(OBu)(2)(acac)(2)] and the smaller cluster [Ti(2)Zr(4)O(4)(OMc)(16)]. In contrast, the same reaction with [Zr(6)O(4)(OH)(4)(OOCR)(12)](2)·6RCOOH (R...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
WILEY-VCH Verlag
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4535662/ https://www.ncbi.nlm.nih.gov/pubmed/26300687 http://dx.doi.org/10.1002/ejic.201500193 |