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Rapid Asymmetric Transfer Hydroformylation (ATHF) of Disubstituted Alkenes Using Paraformaldehyde as a Syngas Surrogate

As an alternative to conventional asymmetric hydroformylation (AHF), asymmetric transfer hydroformylation (ATHF) by using formaldehyde as a surrogate for syngas is reported. A catalyst derived from commercially available [Rh(acac)(CO)(2)] (acac=acetylacetonate) and 1,2-bis[(2S,5S)-2,5-diphenylphosph...

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Detalles Bibliográficos
Autores principales: Fuentes, José A, Pittaway, Rachael, Clarke, Matthew L
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4539593/
https://www.ncbi.nlm.nih.gov/pubmed/26114239
http://dx.doi.org/10.1002/chem.201502049

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