Aminomaleimide fluorophores: a simple functional group with bright, solvent dependent emission

Amino-substituted maleimides form a new class of highly emissive compounds, with large Stokes shifts (>100 nm) and high quantum yields (up to ∼60%). Emission is responsive to the maleimide's environment with both a red-shift, and quenching, observed in protic polar solvents. Aminomaleimides...

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Detalles Bibliográficos
Autores principales: Mabire, Anne B., Robin, Mathew P., Quan, Wen-Dong, Willcock, Helen, Stavros, Vasilios G., O'Reilly, Rachel K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4540011/
https://www.ncbi.nlm.nih.gov/pubmed/25985397
http://dx.doi.org/10.1039/c5cc02908b
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author Mabire, Anne B.
Robin, Mathew P.
Quan, Wen-Dong
Willcock, Helen
Stavros, Vasilios G.
O'Reilly, Rachel K.
author_facet Mabire, Anne B.
Robin, Mathew P.
Quan, Wen-Dong
Willcock, Helen
Stavros, Vasilios G.
O'Reilly, Rachel K.
author_sort Mabire, Anne B.
collection PubMed
description Amino-substituted maleimides form a new class of highly emissive compounds, with large Stokes shifts (>100 nm) and high quantum yields (up to ∼60%). Emission is responsive to the maleimide's environment with both a red-shift, and quenching, observed in protic polar solvents. Aminomaleimides are easily functionalised, providing a versatile fluorescent probe.
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spelling pubmed-45400112015-09-09 Aminomaleimide fluorophores: a simple functional group with bright, solvent dependent emission Mabire, Anne B. Robin, Mathew P. Quan, Wen-Dong Willcock, Helen Stavros, Vasilios G. O'Reilly, Rachel K. Chem Commun (Camb) Chemistry Amino-substituted maleimides form a new class of highly emissive compounds, with large Stokes shifts (>100 nm) and high quantum yields (up to ∼60%). Emission is responsive to the maleimide's environment with both a red-shift, and quenching, observed in protic polar solvents. Aminomaleimides are easily functionalised, providing a versatile fluorescent probe. Royal Society of Chemistry 2015-06-14 2015-05-18 /pmc/articles/PMC4540011/ /pubmed/25985397 http://dx.doi.org/10.1039/c5cc02908b Text en This journal is © The Royal Society of Chemistry 2015 https://creativecommons.org/licenses/by/3.0/This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/ (https://creativecommons.org/licenses/by/3.0/) ) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Mabire, Anne B.
Robin, Mathew P.
Quan, Wen-Dong
Willcock, Helen
Stavros, Vasilios G.
O'Reilly, Rachel K.
Aminomaleimide fluorophores: a simple functional group with bright, solvent dependent emission
title Aminomaleimide fluorophores: a simple functional group with bright, solvent dependent emission
title_full Aminomaleimide fluorophores: a simple functional group with bright, solvent dependent emission
title_fullStr Aminomaleimide fluorophores: a simple functional group with bright, solvent dependent emission
title_full_unstemmed Aminomaleimide fluorophores: a simple functional group with bright, solvent dependent emission
title_short Aminomaleimide fluorophores: a simple functional group with bright, solvent dependent emission
title_sort aminomaleimide fluorophores: a simple functional group with bright, solvent dependent emission
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4540011/
https://www.ncbi.nlm.nih.gov/pubmed/25985397
http://dx.doi.org/10.1039/c5cc02908b
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