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Continuous Flow Metathesis for Direct Valorization of Food Waste: An Example of Cocoa Butter Triglyceride

[Image: see text] The direct chemical conversion of cocoa butter triglycerides, a material available as a postmanufacture waste stream from the food industry, to 1-decene by way of ethenolysis is reported. The conversion of the raw waste material was made possible by use of 1 mol % of the [RuCl(2)(i...

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Detalles Bibliográficos
Autores principales: Schotten, Christiane, Plaza, Dorota, Manzini, Simone, Nolan, Steven P., Ley, Steven V., Browne, Duncan L., Lapkin, Alexei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4547494/
https://www.ncbi.nlm.nih.gov/pubmed/26322250
http://dx.doi.org/10.1021/acssuschemeng.5b00397
Descripción
Sumario:[Image: see text] The direct chemical conversion of cocoa butter triglycerides, a material available as a postmanufacture waste stream from the food industry, to 1-decene by way of ethenolysis is reported. The conversion of the raw waste material was made possible by use of 1 mol % of the [RuCl(2)(iBu-phoban)(2)(3-phenylindenyl)] catalyst. The process has been investigated in both batch and flow conditions, where the latter approach employs a Teflon AF-2400 tube-in-tube gas–liquid membrane contactor to deliver ethylene to the reaction system. These preliminary studies culminate in a continuous processing system, which maintained a constant output over a 150 min period tested.