Crystal structure of ammonium bis­[(pyridin-2-yl)meth­yl]ammonium dichloride

In the title molecular salt, C(12)H(14)N(3) (+)·NH(4) (+)·2Cl(−), the central, secondary-amine, N atom is protonated. The bis­[(pyridin-2-yl)meth­yl]ammonium and ammonium cations both lie across a twofold rotation axis. The dihedral angles between the planes of the pyridine rings is 68.43 (8)°. In t...

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Detalles Bibliográficos
Autores principales: Trischler, Aaron, Oshin, Kayode, Pintauer, Tomislav
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555372/
https://www.ncbi.nlm.nih.gov/pubmed/26396908
http://dx.doi.org/10.1107/S2056989015015753
Descripción
Sumario:In the title molecular salt, C(12)H(14)N(3) (+)·NH(4) (+)·2Cl(−), the central, secondary-amine, N atom is protonated. The bis­[(pyridin-2-yl)meth­yl]ammonium and ammonium cations both lie across a twofold rotation axis. The dihedral angles between the planes of the pyridine rings is 68.43 (8)°. In the crystal, N—H⋯N and N—H⋯Cl hydrogen bonds link the components of the structure, forming a two-dimensional network parallel to (010). In addition, weak C—H⋯Cl hydrogen bonds exist within the two-dimensional network.

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