Crystal structure of ammonium bis­[(pyridin-2-yl)meth­yl]ammonium dichloride

In the title molecular salt, C(12)H(14)N(3) (+)·NH(4) (+)·2Cl(−), the central, secondary-amine, N atom is protonated. The bis­[(pyridin-2-yl)meth­yl]ammonium and ammonium cations both lie across a twofold rotation axis. The dihedral angles between the planes of the pyridine rings is 68.43 (8)°. In t...

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Autores principales: Trischler, Aaron, Oshin, Kayode, Pintauer, Tomislav
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555372/
https://www.ncbi.nlm.nih.gov/pubmed/26396908
http://dx.doi.org/10.1107/S2056989015015753
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author Trischler, Aaron
Oshin, Kayode
Pintauer, Tomislav
author_facet Trischler, Aaron
Oshin, Kayode
Pintauer, Tomislav
author_sort Trischler, Aaron
collection PubMed
description In the title molecular salt, C(12)H(14)N(3) (+)·NH(4) (+)·2Cl(−), the central, secondary-amine, N atom is protonated. The bis­[(pyridin-2-yl)meth­yl]ammonium and ammonium cations both lie across a twofold rotation axis. The dihedral angles between the planes of the pyridine rings is 68.43 (8)°. In the crystal, N—H⋯N and N—H⋯Cl hydrogen bonds link the components of the structure, forming a two-dimensional network parallel to (010). In addition, weak C—H⋯Cl hydrogen bonds exist within the two-dimensional network.
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spelling pubmed-45553722015-09-22 Crystal structure of ammonium bis­[(pyridin-2-yl)meth­yl]ammonium dichloride Trischler, Aaron Oshin, Kayode Pintauer, Tomislav Acta Crystallogr E Crystallogr Commun Data Reports In the title molecular salt, C(12)H(14)N(3) (+)·NH(4) (+)·2Cl(−), the central, secondary-amine, N atom is protonated. The bis­[(pyridin-2-yl)meth­yl]ammonium and ammonium cations both lie across a twofold rotation axis. The dihedral angles between the planes of the pyridine rings is 68.43 (8)°. In the crystal, N—H⋯N and N—H⋯Cl hydrogen bonds link the components of the structure, forming a two-dimensional network parallel to (010). In addition, weak C—H⋯Cl hydrogen bonds exist within the two-dimensional network. International Union of Crystallography 2015-08-29 /pmc/articles/PMC4555372/ /pubmed/26396908 http://dx.doi.org/10.1107/S2056989015015753 Text en © Trischler et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Trischler, Aaron
Oshin, Kayode
Pintauer, Tomislav
Crystal structure of ammonium bis­[(pyridin-2-yl)meth­yl]ammonium dichloride
title Crystal structure of ammonium bis­[(pyridin-2-yl)meth­yl]ammonium dichloride
title_full Crystal structure of ammonium bis­[(pyridin-2-yl)meth­yl]ammonium dichloride
title_fullStr Crystal structure of ammonium bis­[(pyridin-2-yl)meth­yl]ammonium dichloride
title_full_unstemmed Crystal structure of ammonium bis­[(pyridin-2-yl)meth­yl]ammonium dichloride
title_short Crystal structure of ammonium bis­[(pyridin-2-yl)meth­yl]ammonium dichloride
title_sort crystal structure of ammonium bis­[(pyridin-2-yl)meth­yl]ammonium dichloride
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555372/
https://www.ncbi.nlm.nih.gov/pubmed/26396908
http://dx.doi.org/10.1107/S2056989015015753
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