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Crystal structure of 1,1′-{(pentane-1,5-di­yl)bis[(aza­niumylyl­idene)methanylyl­idene]}bis(naphthalen-2-olate)

The whole mol­ecule of the title compound, C(27)H(26)N(2)O(2), is generated by twofold rotational symmetry, with the central C atom of the pentyl chain located on the twofold rotation axis. The compound crystallizes as a bis-zwitterion, and there are two intra­molecular N—H⋯O hydrogen bonds generati...

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Detalles Bibliográficos
Autores principales: Ouari, Kamel, Merzougui, Moufida, Karmazin, Lydia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555373/
https://www.ncbi.nlm.nih.gov/pubmed/26396836
http://dx.doi.org/10.1107/S2056989015014437
Descripción
Sumario:The whole mol­ecule of the title compound, C(27)H(26)N(2)O(2), is generated by twofold rotational symmetry, with the central C atom of the pentyl chain located on the twofold rotation axis. The compound crystallizes as a bis-zwitterion, and there are two intra­molecular N—H⋯O hydrogen bonds generating S(6) ring motifs. In the crystal, mol­ecules are linked by pairs of C—H⋯O hydrogen bonds, forming ribbons propagating along [001], and enclosing R (2) (2)(22) ring motifs.