Crystal structure of 1,1′-{(pentane-1,5-di­yl)bis[(aza­niumylyl­idene)methanylyl­idene]}bis(naphthalen-2-olate)

The whole mol­ecule of the title compound, C(27)H(26)N(2)O(2), is generated by twofold rotational symmetry, with the central C atom of the pentyl chain located on the twofold rotation axis. The compound crystallizes as a bis-zwitterion, and there are two intra­molecular N—H⋯O hydrogen bonds generati...

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Autores principales: Ouari, Kamel, Merzougui, Moufida, Karmazin, Lydia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555373/
https://www.ncbi.nlm.nih.gov/pubmed/26396836
http://dx.doi.org/10.1107/S2056989015014437
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author Ouari, Kamel
Merzougui, Moufida
Karmazin, Lydia
author_facet Ouari, Kamel
Merzougui, Moufida
Karmazin, Lydia
author_sort Ouari, Kamel
collection PubMed
description The whole mol­ecule of the title compound, C(27)H(26)N(2)O(2), is generated by twofold rotational symmetry, with the central C atom of the pentyl chain located on the twofold rotation axis. The compound crystallizes as a bis-zwitterion, and there are two intra­molecular N—H⋯O hydrogen bonds generating S(6) ring motifs. In the crystal, mol­ecules are linked by pairs of C—H⋯O hydrogen bonds, forming ribbons propagating along [001], and enclosing R (2) (2)(22) ring motifs.
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spelling pubmed-45553732015-09-22 Crystal structure of 1,1′-{(pentane-1,5-di­yl)bis[(aza­niumylyl­idene)methanylyl­idene]}bis(naphthalen-2-olate) Ouari, Kamel Merzougui, Moufida Karmazin, Lydia Acta Crystallogr E Crystallogr Commun Research Communications The whole mol­ecule of the title compound, C(27)H(26)N(2)O(2), is generated by twofold rotational symmetry, with the central C atom of the pentyl chain located on the twofold rotation axis. The compound crystallizes as a bis-zwitterion, and there are two intra­molecular N—H⋯O hydrogen bonds generating S(6) ring motifs. In the crystal, mol­ecules are linked by pairs of C—H⋯O hydrogen bonds, forming ribbons propagating along [001], and enclosing R (2) (2)(22) ring motifs. International Union of Crystallography 2015-08-06 /pmc/articles/PMC4555373/ /pubmed/26396836 http://dx.doi.org/10.1107/S2056989015014437 Text en © Ouari et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Ouari, Kamel
Merzougui, Moufida
Karmazin, Lydia
Crystal structure of 1,1′-{(pentane-1,5-di­yl)bis[(aza­niumylyl­idene)methanylyl­idene]}bis(naphthalen-2-olate)
title Crystal structure of 1,1′-{(pentane-1,5-di­yl)bis[(aza­niumylyl­idene)methanylyl­idene]}bis(naphthalen-2-olate)
title_full Crystal structure of 1,1′-{(pentane-1,5-di­yl)bis[(aza­niumylyl­idene)methanylyl­idene]}bis(naphthalen-2-olate)
title_fullStr Crystal structure of 1,1′-{(pentane-1,5-di­yl)bis[(aza­niumylyl­idene)methanylyl­idene]}bis(naphthalen-2-olate)
title_full_unstemmed Crystal structure of 1,1′-{(pentane-1,5-di­yl)bis[(aza­niumylyl­idene)methanylyl­idene]}bis(naphthalen-2-olate)
title_short Crystal structure of 1,1′-{(pentane-1,5-di­yl)bis[(aza­niumylyl­idene)methanylyl­idene]}bis(naphthalen-2-olate)
title_sort crystal structure of 1,1′-{(pentane-1,5-di­yl)bis[(aza­niumylyl­idene)methanylyl­idene]}bis(naphthalen-2-olate)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555373/
https://www.ncbi.nlm.nih.gov/pubmed/26396836
http://dx.doi.org/10.1107/S2056989015014437
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AT karmazinlydia crystalstructureof11pentane15diylbisazaniumylylidenemethanylylidenebisnaphthalen2olate

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