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Crystal structure of N-(2-{[2,6-bis­(2,2,2-tri­fluoro­acetamido)­phen­yl]disulfan­yl}-3-(2,2,2-tri­fluoro­acetamido)­phen­yl)-2,2,2-tri­fluoro­acetamide

The title compound, C(20)H(10)F(12)N(4)O(4)S(2), is an organic diaryl di­sulfide compound with tri­fluoro­acetamide substituents at the ortho-positions of each benzene ring. There are two mol­ecules (labeled A and B) in the asymmetric unit. The F atoms of three of the –CF(3) groups exhibit rotationa...

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Autores principales: Awasabisah, Dennis, Powell, Douglas R., Richter-Addo, George B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555375/
https://www.ncbi.nlm.nih.gov/pubmed/26396879
http://dx.doi.org/10.1107/S2056989015014231
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author Awasabisah, Dennis
Powell, Douglas R.
Richter-Addo, George B.
author_facet Awasabisah, Dennis
Powell, Douglas R.
Richter-Addo, George B.
author_sort Awasabisah, Dennis
collection PubMed
description The title compound, C(20)H(10)F(12)N(4)O(4)S(2), is an organic diaryl di­sulfide compound with tri­fluoro­acetamide substituents at the ortho-positions of each benzene ring. There are two mol­ecules (labeled A and B) in the asymmetric unit. The F atoms of three of the –CF(3) groups exhibit rotational disorder over two positions each. The S—S bond distances are 2.0914 (7) and 2.0827 (6) Å for mol­ecules A and B, respectively. The dihedral angle between the S—S—C and S—C—C planes is 103.05 (15)° for mol­ecule A and 104.09 (15)° for mol­ecule B. The three-dimensional supra­molecular architecture of the crystal is sustained by numerous N—H⋯O, N—H⋯S and C—H⋯O inter­actions.
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spelling pubmed-45553752015-09-22 Crystal structure of N-(2-{[2,6-bis­(2,2,2-tri­fluoro­acetamido)­phen­yl]disulfan­yl}-3-(2,2,2-tri­fluoro­acetamido)­phen­yl)-2,2,2-tri­fluoro­acetamide Awasabisah, Dennis Powell, Douglas R. Richter-Addo, George B. Acta Crystallogr E Crystallogr Commun Data Reports The title compound, C(20)H(10)F(12)N(4)O(4)S(2), is an organic diaryl di­sulfide compound with tri­fluoro­acetamide substituents at the ortho-positions of each benzene ring. There are two mol­ecules (labeled A and B) in the asymmetric unit. The F atoms of three of the –CF(3) groups exhibit rotational disorder over two positions each. The S—S bond distances are 2.0914 (7) and 2.0827 (6) Å for mol­ecules A and B, respectively. The dihedral angle between the S—S—C and S—C—C planes is 103.05 (15)° for mol­ecule A and 104.09 (15)° for mol­ecule B. The three-dimensional supra­molecular architecture of the crystal is sustained by numerous N—H⋯O, N—H⋯S and C—H⋯O inter­actions. International Union of Crystallography 2015-08-06 /pmc/articles/PMC4555375/ /pubmed/26396879 http://dx.doi.org/10.1107/S2056989015014231 Text en © Awasabisah et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Awasabisah, Dennis
Powell, Douglas R.
Richter-Addo, George B.
Crystal structure of N-(2-{[2,6-bis­(2,2,2-tri­fluoro­acetamido)­phen­yl]disulfan­yl}-3-(2,2,2-tri­fluoro­acetamido)­phen­yl)-2,2,2-tri­fluoro­acetamide
title Crystal structure of N-(2-{[2,6-bis­(2,2,2-tri­fluoro­acetamido)­phen­yl]disulfan­yl}-3-(2,2,2-tri­fluoro­acetamido)­phen­yl)-2,2,2-tri­fluoro­acetamide
title_full Crystal structure of N-(2-{[2,6-bis­(2,2,2-tri­fluoro­acetamido)­phen­yl]disulfan­yl}-3-(2,2,2-tri­fluoro­acetamido)­phen­yl)-2,2,2-tri­fluoro­acetamide
title_fullStr Crystal structure of N-(2-{[2,6-bis­(2,2,2-tri­fluoro­acetamido)­phen­yl]disulfan­yl}-3-(2,2,2-tri­fluoro­acetamido)­phen­yl)-2,2,2-tri­fluoro­acetamide
title_full_unstemmed Crystal structure of N-(2-{[2,6-bis­(2,2,2-tri­fluoro­acetamido)­phen­yl]disulfan­yl}-3-(2,2,2-tri­fluoro­acetamido)­phen­yl)-2,2,2-tri­fluoro­acetamide
title_short Crystal structure of N-(2-{[2,6-bis­(2,2,2-tri­fluoro­acetamido)­phen­yl]disulfan­yl}-3-(2,2,2-tri­fluoro­acetamido)­phen­yl)-2,2,2-tri­fluoro­acetamide
title_sort crystal structure of n-(2-{[2,6-bis­(2,2,2-tri­fluoro­acetamido)­phen­yl]disulfan­yl}-3-(2,2,2-tri­fluoro­acetamido)­phen­yl)-2,2,2-tri­fluoro­acetamide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555375/
https://www.ncbi.nlm.nih.gov/pubmed/26396879
http://dx.doi.org/10.1107/S2056989015014231
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